Equilibrium Flashcards

1
Q

Equilibrium constant Kc

A

Kc = [products at their orders] / [reactants at their orders]

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2
Q

Kc values guide

A

Kc = 1 means that the position of equilibrium is halfway between reactants and products.
Kc > 1 means that equilibrium is towards the products
Kc < 1 means that equilibrium is towards the reactants.

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3
Q

Types of equilibria

A

Homogenous

Heterogenous

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4
Q

What does heterogenous equilibrium contain?

A

Species in different states and phases, however the Kc equation only includes the ones that are gases or aqueous.

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5
Q

What does homogenous equilibrium contain?

A

All species are the same and gases.

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6
Q

Equilibrium constant Kp

A

Kp = p(products)^m / p(reactants)^n

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7
Q

Partial pressure

A

The contribution of a gas towards the total pressure.

p(X) = mole fraction of X * total pressure

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8
Q

Mole fraction

A

mole fraction (X) = number of moles of X / total number of moles

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9
Q

Effects on Kp with changing temperature

A
Exothermic:
Increasing temp => Kp decreases
Decreasing temp => Kp increases
Endothermic
Increasing temperature => Kp increases
Decreasing temperature => Kp decreases
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