Equilibrium Flashcards

1
Q

Keq=…

A

ratio of products to reactants at equilibrium, function of pH,P and T

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2
Q

Keq«1 means

A

almost all reactants, barely proceeds

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3
Q

Keq»1 means

A

goes to completion, almost all products

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4
Q

Kw=

A

1x10^-14

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5
Q

Kow=

A

S(org)/S(aq)

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6
Q

POP traits…

A
  1. persistance, 2.toxicity, 3.bioaccumulation
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7
Q

Le Chatilier’s Principle defines what as stress?

A

Tempreture, pressure or concentration change.

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8
Q

What happens when temp. is increased?

A

shifts towards the endothermic +H

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9
Q

What happens when temp. is decreased?

A

shifts towards exothermic -H.

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10
Q

What happens when volume is increased?

A

shifts right

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11
Q

What happens when volume is decreased?

A

shifts left

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12
Q

What happens when pressure is decreased?

A

shifts right

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13
Q

What happens when pressure is increased?

A

shifts left

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14
Q

What happens when an inert gas is added?

A

nothing.

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15
Q

What happens when products are added?

A

shifts left

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16
Q

What happens when products are removed?

A

shifts right

17
Q

Ideal gas law:

A

PV=nRT

18
Q

Q>K means

A

that the rxn shifts left

19
Q

Q<K means

A

that the rxn shifts right