Equilibria Flashcards

1
Q

Define dynamic equilibrium

A

At equilibrium the rate of the forward reaction equals the rate of the reverse reaction

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2
Q

What are the conditions required?

A
  • Reversible reaction
  • Closed system
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3
Q

Define a closed system

A

A system where no exchange of matter takes place

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4
Q

Le Chatelier’s Principle

A

Equilibrium shifts to oppose changes in temperature, pressure or concentration.

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5
Q

Increasing temperature on an exothermic reaction

A

* Increasing temperature will shift the equilibrium to the left
* It will favour the backwards reaction as it is endothermic
* Yield of products decreases

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6
Q

Increasing temperature on an endothermic reaction

A
  • Increasing temperature will shift the equilibrium to the right
  • It will favour the forwards reaction as it is endothermic
  • Yield of products increases
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7
Q

Increasing pressure when reactants have fewer moles

A

* Increasing pressure will shift the equilibrium to the left
* It will favour the side that has fewer moles of gas
* Yield of products decreases.

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8
Q

Increasing pressure when products have fewer moles

A

* Increasing pressure will shift the equilibrium to the right
* It will favour the side that has fewer moles of gas
* Yield of products increases

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9
Q

Increasing pressure with an equal number of moles of gas on both sides

A
  • No effect.
  • Increasing the pressure will speed up both the forward and backwards reaction by the same amount
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