Equations to know Flashcards
When trying to gauge the likelihood of a gene or a combination, how are they found?
If you wanted a homozygous tall plant from a TtPp the likelihood of that is 1/4 the likelihood is 1/16(1/4x1/4) so they are multiplied.
Whereas the likelihood of getting a certain trait found above can be added if there are multiple ways to receive it.
add the different likelihoods
How is the total lung capacity found?
Total lung capacity=residual volume+vital capacity
How is the Vital capacity found?
Vital capacity=tidal volume+expiratory reserve volume+inspiratory reserve volume
What is the hardy weiinberg equilibrium equation?
p^2+2pq+q^2=1
with only two possible choices at the gene locus p+q=1.
What is the equation for specific rotation?
α=αo/Cxl
or specific rotation=observed rotation/(concentration (g/mL)xlength(dm))
What is the equation to find frequency?
f=c/λ
What is the Henderson-hasselbach equation?
pH=pKa+log((conj base)/(conj acid))
What is the value of a charge of a proton/electron?
• (1.6 × 10− 19 C)
What is 1 atomic mass unit equal to/
•1amu=1.66 × 10− 24 grams
What is avogardro’s number?
• 1mol=Avogadro’s number: 6.022 × 1023
What is the electromagnetic energy and frequency equation?
•E=hf=hc/λ J=(Js)(1/s)=(Js)(m/s)(1/m). h=6.626x10^-34 Planck’s constant
c=speed of light 3x10^8
What is the equation for angular momentum?
•angular momentum=L=mvr kintetic energy=KE=1/2mv^2
How is the electromagnetic energy found from the energy levels?
E=hf=-RH((1/ni^2)-(1/nf^2))
n=quantum number, RH= rhydberg constant=2.18x10-18 J/electron, speed of light= c= 3x108 m/s
• n > 2 energy level to the n = 2 energy level is known, the Balmer series and includes four wavelengths in the visible region
• n > 1 to n = 1 (that is, the emissions of photons from the electron falling from the higher energy levels to the ground state) is called the Lyman series, which includes larger energy transitions and therefore shorter photon wavelengths in the UV region of the electromagnetic spectrum.
What is the angular momentum given the energy level of the series?
L=nh/2π
h=6.626x10-34 Planck’s constant
What is the maximum number of electrons that can exist in a subshell?
4l + 2
where l is the azimuthal number l=(0-3)
for any value of l there is a maximum 2l+l possible values for the magnetic quantum number ml. with each orbital holding -∞,0,∞
What is the pattern of the periodic table?
- Left → Right
- Atomic radius ↓
- Ionization energy ↑
- Electron affinity ↑
- Electronegativity ↑
- Top → Bottom
- Atomic radius ↑
- Ionization energy ↓
- Electron affinity ↓
- Electronegativity ↓
What is the equation for a vector quantity?
μ=qr
. μ =vector quantity. q=charge magnitude r=distance between two partial charges
What is the equation to find formal charge?
Formal charge= V-Nnonbonding-1/2Nnonbonding.
where v is the normal number of electrons in the atom’s valence shell, N nonbonding is the number of bonding electrons
What is the atmosphere conversion?
1atm=760mmHg=760torr=101.325kPa
What is the standard temperature and pressure, and the standard state conditions?
STP=273.17, (0C) and 1atm.
Standard state=298K, and 1atm
How can the average kinetic energy of gas particles be found?
KE=1/2mv^2=3/2kT
where k=boltzmann constant=1.3806488 × 10-23 m^2 kg s^-2 K^-1
J=(kg)(m/s)^2=(J/K)(K)
How can the resultant quantity of speed be found?
Urms=√((3RT)/M)
R is the ideal gas constant=8.3144621 J K^−1 mol^−1
T is the temperature, and M is the molecular mass
What is Graham’s law and what does it determine?
r1/r2=√(M2/M1)
r=diffusion rates of gas 1 and 2, M=molar mass
equation used to determine the relative rates of diffusion or effusion
What does avogadro’s principle sate about gases at constant temperature and pressure?
n/V=k
n=moles of gas, V=volume
k=boltzmann constant=1.3806488 × 10-23 m^2 kg s^-2 K^-1
or n1/V1=n2/V2
What is the ideal gas law?
PV=nRT when comparing two gases withe the same moles the equations P1V1/T1=P2V2/T2 can be used
V2=(V1(P1/P2)(T2/T1))
where n is the number of moles found by n=m(mass in grams)/M(molar mass)
R=8.21 × 10-2 (L· atm)/(mol· K) or 8.314 J/(K· mol)
HOW can density be found?
density=mass/Volume. or m=dstp/Vstp=dstp/22.4L/mol
What is Boyle’s Law?
constant temperature.
PV=k or P1V1=P2V2
as pressure increases volume decreases
What is Charle’s Law?
constant pressure
V/T=k or V1/T2=V2/T2
as one increases so does the other
What is dalton’s law?
PT=PA+PB+PC+…
How is the partial pressure of a gas related to its mole fraction?
PA=PTX
where X=mole fraction
PA= the partial pressure of the gas
PT=total pressure
with the mole fraction found by XA=nA/nt or (moles of A/total moles of gases)
What is the Van der waals equation of state?
(P+((n^2a)/V^2))(V-nb)=nRT
where a and b are physical constants experimentally determined for each gas. The a term corrects for the attractive forces between molecules (a for attractive) and as such will be smaller for gases that are small and less polarizable He, larger for gases that are larger and more polarizable Xe, and largest for polar molecules. The b term corrects for the volume of the molecules themselves. Larger values of b are thus found for larger molecules. Numerical values for a are generally much larger than those for b.
What is the gram equivalent weight?
gram equivalent weight=molar mass/n
where n is the number of moles of something donated
What is the equation for equivalents?
equivalents=mass of compound/gram equivalent weight
What is the equation for molarity?
Molarity=Normality/n
How is normality found?
it is a measure of concentration and is measured in equivalents/liter, 1N solution has a concentration of hydrogen ions equal to 1 mole/liter
What is an empirical formula?
gives the simplest whole number ratio of the elements int he compound
What is a molecular formula?
gives the exact number of atoms of each element in the compound and is a multiple of the empirical
How is percent composition found?
% composiiton=(mass of X in formula/formula weight of compound) x100%
How is percent yield found?
percent yield=(actual yield/theoretical yield)x100%
What is the rate law?
-Δ(A)/aΔt=-Δ(B)/bΔt=-Δ(C)/cΔt=-Δ(D)/dΔt
where aA+bB=cC+dD
What is the rate equation?
rate=k(A)^x(B)^y
mole/Ls=k(mol/L)^x*(mole/L)^y
what is the equation for a zero order reaction?
first order?
second order?
mixed order?
rate=k(A)^0*(B)^0)=k
rate=k(A)^1 or rate=k(B)^1
with rate=-Δ(A)/Δt=kA and the At=(A0)e^-kt
rate=k(A)^1(B)^1 or rate=k(A)^0(B)^2=kB^2 or rate=k(A)^2*(B)^0=kA^2
rate=(k1(E)(A^2))/(k2+k3(A))
What is the rate of a reaction when there is an energy barrier given the requirement of activation energy?
rate=fZ
Z is the total number of collisions occurring per second, f is the fraction of collisions that are effective
how is the equilibrium constant found? What is the law of mass action?
kf/kr=(B)(C)/(A) where kf and kr are constants and can in turn be used to find kc, kr/kr=Kc=Keq
keq=Kc=(k^1k^2k^3)/(k^-1k^-2k^-3)=((C)^c(D)^d)/((A)^a(B)^b)
units of concentration are mol/L
What is the equation for the reaction quotient?
In what instances is the reaction quotient different than the equilibrium constant and what does it suggest?
Qc==((C)^c(D)^d)/((A)^a(B)^b)
- Qc < Keq, Δ G < 0, reaction proceeds in forward direction
- Qc = Keq, Δ G = 0, reaction is in dynamic equilibrium
- Qc > Keq, Δ G > 0, reaction proceeds in reverse direction
What is the equation for internal energy?
ΔU=Q-W
change in the total internal energy (Δ U) of a system is equal to the amount of heat (thermal energy) transferred (Q) to the system minus the amount of work (W) all in joules
no heat exchanged means
Δ Usystem + Δ Usurroundings = Δ Ucalorimeter = Qcalorimeter− Wcalorimeter = 0.
no work done so qsystem = − qsurroundings, and msteelcsteelΔ T + moxygencoxygenΔ T = − mwatercwaterΔ T.
What is the equation for specific heat?
q=mcΔT
J=(g)(J/G*K)(K)
where q is the heat absorbed or released, m is the mass, c is the specific heat, and T is the change in temperature
What is the equation for enthalpy change?
ΔH=Hproducts-Hreactants
J=J-J
What is the bond dissociation energy equation?
ΔH=ΣΔHbonds broken+ΣΔHbonds formed= total energy absorbed-total energy released
What is the equation to find the change in entropy of a reaction?
ΔS=Qrev/T
where Qrev is the heat that is gained or lost in the reversible process
kJ/molK
ΔSorxn=ΣΔSoproducts-ΣΔSoreactants
ΔS=ΔSfinal-ΔSinitial
What is the equation for the total change in entropy of the universe?
ΔSuniverse=ΔSsystem+ΔSsurroundings>0
What is the equation for Gibbs free energy?
ΔG=ΔH-TΔS
J/moll=(J/mol)-(K)(J/molK)
What is the standard gibbs free energy equation of a reaction?
ΔGorxn=Σ(ΔGoproducts)-Σ(ΔGoreactants)
What is the equation for the standard gibbs free energy of a particular reaction?
ΔGo=-RTlnKeq
J/mol=(J/molK)(K)(dimensionless)
What is the equation for the gibbs free energy of a particular reaction?
ΔG=ΔGo+RTlnQ
Wat is the gibes function of the gas-solid equilibrium?
ΔG=G(g)-G(s)
G(g)=G(s) because the change in gibbs free energy must be equal to zero in the phase equilibria
What is the equation for vapor pressure depression?
ΔP=PAo-PA
What is Raoult’s law?
ΔPA=XAPAo
XA is the mole fraction of the solute
atm=atm
What is the equation of the boiling point elevation?
ΔTb=iKbm
where i is the cant hoff factor or the moles of particles dissolved into a solution per mole of solute molecule, and Kb is a proportionally constant characteristic of a particular solvent m is the molality o the solution (molalilty=moles of solute/kg of solvent)
K=(K/molal)(molal)
What is the equation for freezing point depression?
ΔTb=iKfm
where i is the cant hoff factor or the moles of particles dissolved into a solution per mole of solute molecule, and Kf is a proportionally constant characteristic of a particular solvent m is the molality o the solution (molalilty=moles of solute/kg of solvent)
K=(K/molal)(molal)
What is the equation for osmotic pressure?
Π=iMRT
, defined as the osmotic pressure (Π ) where M is the molarity of the solution, R is the ideal gas constant, T is the absolute temperature (in Kelvin), and i is the van’t Hoff factor.
atm=(L/mol)(Latm/molK)(K)
What is the equation for dilutions?
M1V1=M2V2
What is the equation for solution equilibria?
Ksp=(A^n+)^M(B^m-)^n
by the reaction AmBn to mA^n+ + B^m-
What i the equation and units for I.P.?
I.P.=(A^n+)^M(B^m-)^n
mol/L
Ion product analogous to Q compared to Ksp in determining the behavior of the solution when not in equilibrium
What is the equation for finding the pH of a solution?
pH=-log(H+)=log(1/(H+))
What is the equation for finding the pOH of a solution?
pOH=-log(OH-)=log(1/(OH-))
What is the additive effects of the pHs
pH+pOH=14
pH=14-pOH=14-(-log(OH-)=14+log(1)=14+0=14
What is the equilibrium equation for hydrogen and hydroxide concentrations?
Ksp=(H3O+)(OH-)
Kn=(H3O+)(A-)/(HA)
or Kb=(B+)(OH-)//(BOH)
What equation is used to find the volume and normality when things are titrated?
NaVa=NbVb
Na and Nb are the normalities of the acid and base respectively
How can pKa and pKb be found?
pH=pKa+log(conj base/weak acid)
pOH=pKb+log(conj acid/weak base)
What is the equation for standard reduction potentials or standard electromotive force emf?
emfo=Eocell-Eoanode=Eored+Eooxid
What is the change in gibbs free energy of redox reactions?
ΔGo=-nFEocell=-RTlnK
or the change in chemical potential of a reaction, or the change in the amount of energy available in a chemical system to do work. n is the number of moles of electrons exchanged, F is faraday’s constants, and Ecell is the Emf of the cell
ΔG=-nFEcell
What is the equation to find the Ecell?
Ecell=Eocell-(RT/nF)lnQ
What equation is used to multiple vectors?
B=nA, when a vector A is multiple by a scalar value n, it produces a new vector B
What is the equation for velocity?
v=Δx/Δt
m/s
What is the equation for acceleration?
a=Δv/Δt
m/s^2