equations Flashcards

1
Q

energy of a quantum

A
E = hf 
h = plancks constant
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2
Q

energy of an electron

A
E = -Rh/ n^2 
Rh = Rydberg constant
n= quantum #
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3
Q

energy of an e- is _______ proportional to the principle quantum # (n)

A

directly proportional, bc of the negative sign in the equation, as n increases, gets closer to 0 (thus increasing)

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4
Q

the energy of an e- _________ the further out from the nucleus that is is located

A

increases

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5
Q

electromagnetic energy

A

of photons emitted by e- that return to ground state

E=hc/lambda

h= planck's constant
c = speed of light = 3*10^8
lambda = wavelength
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6
Q

the energy difference between two shells _________ as the distance from the nucleus increases

A

decreases

so the energy diff. between n=3 and n=4 is less than the energy diff. between n=1 and n=2

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7
Q

range of possible values for l (azimuthal quantum #)

A

0 - (n-1)

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8
Q

for any value of n, there will be a max of ______ electrons

A

2n^2

2 per orbital

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9
Q

draw out e- subshell flow diagram

A

do it

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10
Q

E = hc/lambda = ?

A

-Rh*(1/ni^2-1/nf^2)

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11
Q

planck’s constant

A

6.62610^-34 Js

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12
Q

diatomic elements (7)

A
H2
N2
O2
F2
Cl2
Br2
I2
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13
Q

dipole moment equation

A

u= qr

q = charge magnitude
r = distance between 2 partial charges
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14
Q

in lewis structure, which atom is the central atom?

A

the least electronegative

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15
Q

difference between electronic geometry and molecular geometry?

A

electronic includes bonding and lone pairs around central atom

molecular geometry describes spatial arrangement of only the bonding pairs

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16
Q

gram equivalent weight

A

molar mass/n

equiv. weight of a compound is the mass that provides one mole of charge

ex. need 49g of H2SO4 (molar mass=98g/mol) to produce one mole of H+ ions
bc it can donate 2 H’s, n=2

17
Q

equivalents

A

mass of compound / gram equivalent weight

18
Q

normality

A

equivalents/liter

19
Q

molarity

A

normality/ n

20
Q

% composition

A

(mass of X in formula/ formula weight of compound) * 100%

21
Q

percent yield

A

(actual yield/theoretical yield) * 100%

22
Q

what is the only factor that can change the rate of a zero-order rxn?

A

temperature

23
Q

1st law of thermodynamics

A

deltaU = Q-W

total internal energy = heat(Q) - work (W)

24
Q

specific heat equation

A

specific heat (q) = mass (m)* specific heat of substance (c) * delta T (change in temp)

25
Q

specific heat of H20 (l)

A

1 cal/ g*celsius

26
Q

celsius to F equation

A

F = (9/5)*C + 32

27
Q

when do gases deviate from ideal behavior?

A

high pressure, low temp

28
Q

KE =? (in terms of gas molecules)

A

KE = .5mv^2 = (3/2)kT

k = boltzmann constant

29
Q

graham’s law equation

A

r1/r2 = sqrt(M2/M1)

r1 and r2 = rates of diffusion/effusion

30
Q

osmotic pressure equation

A

osmotic pressure = iMRT

i= van’t hoff factor (ex. NaCl, i=2)
M=molarity
R= ideal gas constant
T = temp (K)

31
Q

freezing/boiling pt depression equation

A

deltaT = iKm

i= van’t hoff factor
K= proportionality constant
m=molality

32
Q

all ________ and _______ salts are completelhy soluble

A

all sodium and all nitrate salts are completely soluble

33
Q

strong acids (7)

A
HCl
HBr
HI
H2SO4
HNO3
HClO3
HClO4
34
Q

weak acids (6)

A
HF
HCN
acetic acid
H2O
HSO4-
NH4+
35
Q

strong bases (6)

A
NaOH
KOH
CaOH2
CaO
NaO
NH2-
36
Q

weak bases (6)

A
acetate - CH3COO-
H2O
SO4^2-
CN-
F-
NH3