Equations Flashcards
What is the equation for the low temperature value for M?
If the spins are aligned:
Msat = ngS + n’g’S’
If the spins are opposed:
Msat = ngS - n’g’S’
What is the equation for the Curie law?
χ = C/T
What is the equation for the Curie-Weiss law?
χ = C/(T-θ)
What is the equation for C?
0.500S(S+1)
What is the equation for the magnetic susceptibility, χ?
M/H
What is the equation for C in a ferrimagnet at high temperature?
0.500nS(S+1) + 0.500n’S’(S’+1)
What order coupling do T terms have?
T terms show first order coupling. This produces a temperature dependent moment.
What order coupling do A and E terms have?
A and E terms show second order coupling which is not temperature dependent.
What order coupling do d5 high spin compounds show?
No coupling as there is no orbital moment to quench.