Equations Flashcards
Momentum
p=hbark
Energy of free electron
E=hbar^2k^2/2m
Schrodinger eqn
H|ψ>=E|Ψ>, H|C>=E|C>
Momentum operator
P=-ihar*laplacian
Hamiltonian
H=1/2mP(operator)^2+V=-habr^2/2m*Δ^2+V
Hamiltonian matrix elements
=<Hi|H|Hj>
2nd order perturbation theory
E = E0+<ψn|H|ψn>+Σn’≠n<ψn|Hpert|ψn’>/εn-εn’
LCAO for diatomic molecule
(E1 0 0 E2)(C1 C2) = E (1 S S 1) (C1 C2)
Energy for LCAO when E1=E2=E0
E = Eo±|U|
(C1 C2) when E1=E2
1/root(2)*(1 ±1)
E for LCAO when E1≠E2
E=Eav±root(Ecov^2+Eionic^2)
Ecov
Ecov=2|U|
Eionic
=|E1-E2/2|
Eav
=E1+E2/2
Bloch Theorem
ψ(r+a) = exp(ikr)ψ(r)
Bloch function
ψn(r)=exp(ikr)un(r)
average p
<p>=<ψnk|P|ψnk> = hbark + <Un|p|Un> = Pcrystal ( + Pnn atomic part which =0 when definite parity)
</p>
Effective mass
1/m*=1/hbar^2d^2E/Dk^2=1/m(1+Ep/Eg)
Ep (energy of kane momentum)
Ep=2Pcv^2/m
Energy of dipole in magnetic field
Hso proportional σΔV*P
Vg Group velocity
Vg=dω/dk=1/hbarΔE
acceleration with group velocity
a = dVg/dt=M^-1*F
M^-1
M^-1=1/hbar^dE/dkidkj
Important Lattice Points
L = 1/2[111]2π/a
Γ = [000]
X = [100]2π/α
Bowing
E(x) = EA(1-x)+EBx+bx(1-x)
State radius
an=a0n^2
binding energy
En=-Er/n^2
Number of states per unit volume
g(E)dE=g(k)dK
3D density of states
g(E) proportional m*^3/2E^1/2
2D density of states
g(E) proportional m*E^0
1D density of states
g(E) proportional m*^1/2E^-1/2
boltzmann occupation function
fB(E) proportional exp(-E/kT)
Fermi occupation function
f(E) = 1/(1+exp((E-Ef)/kt)
Number of electrons per unit volume
n=Nc*exp((Ef-Ec)/kt)
Nc
Nc=2(me*kT/2πhbar^2)^3/2
Number of holes per unit volume
p = Nv*exp((Ev-Ef)/kT)
Law of mass action
np=ni^2=NcNv*exp(-Eg/kT)
Fermis golden rule for number of excitations per unit vol
Rcv = 2π/hbar|<c|Hopt|v>/2|^2*gcv(e)
Reduced Mass
1/μ = 1/mc+1/mv (replace m* with μ in DOS formulas for joint density of states)
Intensity
I = F^2/2Z0 = hbarωφ
wavelength in terms of k
λ= 2π/k=2πc/ω=hc/E
current density
J = σε
Drift velocity
vd= με (μ = mobility)
mobility
μ = qτ/μ*
conductivity
σ= 1/ρ = neμ = nq^2τ/m*
Lorentz Force
F = q(ε+vg x B)
Hall Resistance
Rh=1/nq
cyclotron frequency
ωc = qB/m*
Landau level energy
Ε = hbar^2kz^2/2m+(l+1/2)hbarωψ
Lattice Scattering
μl proportional T^-3/2
impurity scattering
μi proportional T^3/2
1/total scattering
1/μ = 1/μl+1/μi
potential
dφ(x)/dx = ε(x)
Gauss’ law for charge density in 1D
dε(x)/dx = 1/ε*ρ(x)
Electric field
ε = F/d = V/d (uniform) = Q/4πε0r^2 (radial)
Magnetic field
B = μ0I/2πr
Magnetic force
F = qvBsin(90) = m*v^2/r (centripetal force)