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ORGO > Epoxides, Ethers, Vicinal Diols > Flashcards

Epoxides, Ethers, Vicinal Diols Flashcards

1
Q

Synthesizing Epoxides Using Halohydrins

A

Br2, H2O

NaH

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2
Q

Synthesizing Epoxides Using mCPBA

A

Concerted donation and acceptance

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3
Q

Opening Epoxides: Acidic Conditions

A

More substituted C

mCPBA

ROH
——->
H+

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4
Q

Opening Epoxides: Basic Conditions

A

Less substituted C

mCPBA

ROH
——–>
NaOCH3

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5
Q

Synthesizing Vicinal Diols: Anti Addition of 2 OH Groups

A

mCPBA

H3O+

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6
Q

Synthesizing Vicinal Diols: Syn Addition of 2 OH Groups

A

mCPBA

OsO4, H2O

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ORGO (12 decks)

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