Environmental physics Flashcards
What is the total work done by the system over the course of the heat engine cycle?
Area contained in a PV diagram
Since heat engine cycles are cyclic processes, what can we say about the integral of the internal energy over the entire cycle?
It equals zero
What is the Carnot cycle (not the steps)?
An idealisation of a heat engine where heat is transferred from a hot reservoir to a cold reservoir
How is the heat transferred in a Carnot cycle?
Via a gas-filled piston which can be isolated from either or both reservoirs
In the Carnot cycle, how is work extracted from the system using the piston?
The gas in the piston expands or contracts depending on which reservoir it is connected to and the raising and lowering of the piston allows work to be extracted
What are the 4 stages of the Carnot cycle?
Isothermal expansion, adiabatic (or isentropic) expansion, isothermal compression and adiabatic (or isentropic) compression
What is the efficiency of any heat engine?
The ratio of the work done to the heat input into the system
What is the efficiency of the Carnot cycle, given that it is a reversible and cyclic process?
Heat in minus heat out all divided by heat in
What are heat pumps?
Reverse Carnot engines
What is the quantification of how good a heat pump is and what is its equation?
Coefficient of performance and heat out over work done
What is Carnot’s theorem?
All Carnot engines operating between reservoirs at given temperatures are equally efficient and no reversible engine is m ore efficient than the Carnot engine.
How do you prove Carnot’s theorem?
Imagine a Carnot engine connected to a heat pump in a system with the efficiency of the engine more than that of the heat pump, then there would be a breach of the second law (heat from cold reservoir into the hot reservoir)
What is a consequence of Carnot’s theorem?
The Carnot cycle is the most efficient possible heat engine operating between reservoirs at specified temperatures
From Carnot’s theorem, what is Q (cold) over Q (hot) equal to?
T (cold) over T (hot)
What is the saturation temperature in regards to steam power?
The particular temperature at which water cannot contain any more heat and stay a liquid (under constant pressure)
After the saturation temperature, the energy from any heat added to the water beyond this point will go towards what?
Converting some of the liquid into vapour, which then increases the volume (not towards increasing the temperature of the water)
When there is no more liquid left to be vaporised (still at the saturation temp), what happens when you continue adding heat?
Temperature will rise again
What does the temperature versus volume graph look like for water under constant pressure that heat is being added to and it turns to vapour?
It rises to the saturation temperature and then plateaus for a bit (liquid and vapour phases coexisting) and then the temperature rises again
Does the volume of pressurised water vapour increase or decrease with increasing pressure?
Decreases
Does the saturation temperature of the water/ vapour phase increase or decrease with increasing pressure?
Increase
What is the critical point on a phase diagram of temperature versus volume for water to vapour transitions?
It is at 674 K at a pressure of around 22 MPa and beyond this point, no phase change can be observed
On either side of the critical point, what are the lines called and what do they represent?
Saturated liquid line, where the transition from a pure liquid to a mixed state is and saturated vapour line, where the transition from mixed to pure vapour state is
What is the liquid called on the liquid side of the saturated liquid line on the temperature volume graph?
Compressed liquid
What is the vapour called on the vapour side of the saturated vapour line on the temperature volume graph?
Superheated vapour
What is the Rankine engine (not the stages)?
A simplified model of a steam turbine systems such as those used in coal and natural gas power plants
What are the 4 stages of the Rankine cycle?
Isentropic compression in a pump, isobaric heating in a boiler, isentropic expansion through a turbine and isobaric condensation in a condenser
What is the isentropic compression in a pump stage in the Rankine cycle?
Liquid water brought to high pressure using a pump without adding any heat
What is the isobaric heating in a boiler stage in the Rankine cycle?
Fixed pressure, water heated in a boiler until entirely evaporated
What is the isentropic expansion through a turbine stage in the Rankine cycle?
Vapour allowed to expand while passing through a turbine from which mechanical work is extracted
What is the isobaric condensation in a condenser stage in the Rankine cycle?
Vapour enters a condenser where it is cooled and returned to a liquid state at constant pressure, before starting the cycle again
In the Rankine cycle, the pump, boiler, turbine and condenser are considered open thermal systems, why?
Material both enter and exits, carrying energy with it
The change in the internal energy in any of the open thermal systems of the Rankine system is of what form?
Change in internal energy of the control volume due to internal processes plus the internal energy change from the material entering the system minus the internal energy change due to material exiting the system
What are the two forms of work done on the contents of the control volume?
Flow work, where work is done by the material coming in and out applying pressure to the contents, and shaft work, where work is being done or by the contents on a n external mechanical component
What is the flow work?
Work done in displacing the contents in the control volume
what is the efficiency of the Rankine cycle?
Specific enthalpy = SE . 1 - (SE of steam passing from turbine to condenser minus SE of water passing from condenser to pump) divided by (SE of steam passing from boiled to turbine minus SE of water passing from pump to boiler)
What is the efficiency of a coal fired power plant and is this good?
23% (overestimate) and no this is very low efficiency
What is the Keeling curve?
The atmospheric carbon dioxide concentration against time
What does the Keeling curve look like?
It increases with time exponentially on average but it is wiggly locally with periodic oscillations
What are the periodic oscillation of the Keeling curve due to?
The seasonal death and regrowth of plant matter in the large boreal forests in North America and Russia
What was the carbon dioxide concentration before the industrial revolution? (found from air bubbles trapped in Antarctic ice cores)
280 parts per million
What are the carbon dioxide concentrations now?
Over 400 parts per million
How is acid rain caused?
Sulphur oxides comes from the exhaust from coal power (as well as carbon) and react with the water content of clouds to form sulphuric acid
What does acid rain do?
It enters soil and interrupts normal biological processed in the microbiome and increases the acidity of the oceans
What is insolation and what letter represents it?
Power per unit area received by a flat surface from the sun and Q
What does the insolation of a given surface depend on?
The angle the normal of the surface makes with a direct line to the sun (more hits surface if perpendicular with sun rays)
What is the solar zenith angle?
The angle between the suns rays and the normal of the curved surface of the Earth at any point
Does the solar zenith angle change with time and why?
Yes because the Earth rotates and orbits the sun
What is the latitude?
Measures the angle going north from the equator (North-South direction)
What is the longitude?
Measure the angle going east from the Greenwich meridian (East-West direction)
What is the obliquity of the ecliptic?
The angle between the ecliptic plane and equatorial plane, the ‘tilt’ of the Earth
What is the ecliptic?
It is the name for the orbital plane of the Earth around the sun
What is the equatorial plane?
The plane through the Earth’s equator
What is a heliocentric and geocentric coordinate system?
Heliocentric one is fixed to the sun and a geocentric one is fixed to the Earth
As the Earth orbits around the sun, what does the geocentric coordinate system do?
They rotate with respect to the heliocentric system
What is the ecliptic longitude (L)?
The celestial longitude measured with respect to the ecliptic plane, I think the angle the geocentric coordinate system makes with respect to the heliocentric system as the Earth orbits the sun
What is the right ascension?
The celestial version of longitude to determine the position of the sun as viewed from the Earth
What is the declination?
The celestial version of latitude to determine the position of the sun as viewed from Earth
Why does the sun move up and down in the sky over the course of a year?
The declination can be put in terms of the obliquity and the ecliptic longitude and this leads to the declination changing as the Earth moves around its orbit
What is the hour angle?
The longitude minus the right ascension
At the astronomical sunrise and sunset, what angle will rays of light be to the Earth’s surface?
Perpendicular so the zenith angle is + or - 90 degrees
When does maximum insolation occur?
On the equinoxes when the sun is directly overhead at noon
What are seasonal variations due to on the equator?
Variation in the declination
On the north pole, when does the sun rise and set?
Rises on the vernal equinox and set on the autumnal equinox
The Earth’s surface temperature changes with seasons, but where does the temperature remain essentially constant?
Deep in the ground
What is the reasoning behind ground source heat pumps?
Since the temp deep underground is nearly constant, we can use the ground as a heat sink to cool a building in the summer and heat it in the winter
The heat flux (flow of energy per unit area per unit time) through a vertical section of the ground obeys what law?
Fourier’s law. Heat flux equal minus the thermal conductivity multiplied by the temperature gradient
What is the heat equation? (used for ground source heat pumps section)
Partial differentiation of temperature with respect to time equals the thermal diffusivity times the second order partial derivative of temperature with respect to time
From the solution the ground temperature equation, why is there a certain depth where the temperature is increased in winter and decreased in summer?
The sign of the cosine in the equation flips in this equation
Are ground source heat pumps an efficient way to heat a room and what is their coefficient of performance?
Yes very efficient and 50
On a PV plane, what does a ground source heat pump look like?
A Rankine cycle
Why are refrigerants used in a vapour compression cycle and what do we use for it at the moment?
They are liquids with low boiling points so it can easily go through repeated phase transitions and propane
If we use a frame of reference where the moon just stays where it is (distance between moon and earth is constant), this avoids needing a centrifugal force but what does it mean we need to consider related to gravity?
The gravitational pull on the Earth due to the moon
For a test mass on Earth’s surface, the angular component of acceleration is called what and what is it responsible for?
Tractive acceleration and it is responsible for the tides
Where does the tide raising force point to on the Earth when the tide-raising body considered is the moon?
The point under the moon and its antipode
Is the tide-raising force from the sun stronger or weaker than the moon and by how much?
Weaker but only 0.46x that of the moon’s force strength
Why do the pair of tidal bulges change in magnitude depending on the relative configuration of the sun-Earth-moon system?
The tide raising force from the sun and moon add vectorially
When are the tidal bulges maximised in relation to the sun-Earth-moon configuration?
when they form a straight line, known as a syzygy, which occurs on full and new moons
What are the maximal and minimal tides called?
Maximal are called spring tides and minimal are called neap tides
When are the tidal bulges minimised in relation to the sun-Earth-moon configuration?
When the sun, Earth and moon form a right angle
What is a sidereal day and sidereal year? sidereal means ‘with respect to the distant stars’
Sidereal day refers to the period of rotation of the Earth with respect to a fixed background and the sidereal year refers to the orbital period of the Earth
What does diurnal and semi-diurnal mean?
A diurnal process is one that is periodic and repeats once per day, whereas a periodic process that repeats twice per day is semi-diurnal
What is a mean solar day?
The time it takes for the sun to cross the sky and return
What is a mean lunar day?
The time it takes for the moon to cross the sky and return
What is the frequency of lunar tides?
Twice per mean lunar day
What is the frequency of solar tides?
Twice per mean solar day
If you combine the amplitude of lunar and solar tides to get a combined tide, what does each term represent?
Two different harmonics of the tidal motion
What is the period of the moon circling the Earth?
One sidereal month
Does the moon’s declination change or stay the same over the course of a day?
It varies
What is the diurnal inequality and why does it exist?
The two tides at a particular point on Earth have different amplitudes because the angle at that place to the moons orbit will be different at each tide time in one day (moon’s orbit is tilted with respect to the Earth’s axis)
What are the labels for the semi-diurnal tides due to the moon and sun and also the label for the diurnal lunar tide from the diurnal inequality?
M2, S2 and O1
As the moon orbits the Earth, it drags the bulge in it but why is there a lag in this?
Inertia, frictional forces and competing rotation means the motion of the bulges cannot keep up with the motion of the moon
The lag between the motion of the bulges and the moon leads to a torque on the Earth, what does this do to the Earth?
It tries to modify the rotation of the Earth to match up with the orbit of the moon
What is tidal locking and why does it occur?
The same face of the moon always faces the Earth because of the tidal acceleration from the Earth creating a torque and the moon’s rate of rotation nearly matches its orbital period so it always faces
When does tidal locking occur?
It appears across the solar system when two bodies have significant tidal interactions
Why is the moon slowly moving away from Earth?
To conserve angular momentum in the Earth-moon system and the Earth’s angular momentum decreases from tidal locking slowing its rotation
What is the tidal range of the open ocean? (amplitude will be half this)
60cm
Why are the tidal ranges of the seaside a lot larger than the tidal range of the open ocean?
As the tides roll in, they are slowed and their kinetic energy gets converted into potential energy (height)
What is tidal resonance?
The fundamental modes of the surface waves in a channel are excited by the tides in the open sea
When does tidal resonance occur?
In narrow channels
What is the simplest way to use tidal power to generate power? (using the tidal range from tidal resonance)
Build a barrier over a channel to capture the water at its high point and let the water escape through a sluice gate (via a turbine) at low tides. Converts GPE into usable energy.
What is another way to use the tides to generate power?
Extract some of the kinetic energy of the tidal currents using a turbine
How was the Earth’s primary atmosphere formed?
A protoplanetary disk was formed around the sun and the planets formed by collisional accretion of dust and gas was swept up by planet cores to make their primordial atmospheres
How was the Earth’s secondary atmosphere formed?
The Earth was hit by a massive impact by a smaller protoplanet, making a freshly molten Earth releasing volatile gases that form the second atmosphere (ie nitrogen, water, methane, CO2). The water from this condensed to form early seas
What are the 3 time periods in Earth’s history called?
Archean Earth, Proterozoic Earth and Modern Earth
Where did the Earth’s atmosphere come from?
Asteroid bombardment, outgassing due to volcanic activity and likely meteorites with chromium nitrate in
When did oxygen show up in the Earth’s atmosphere?
In Earth’s Proterozoic stage 2.5 billion years ago in the ‘Great Oxigination Event’
How did the Argon in our atmosphere originate and what did it not come from?
In potassium decay either through electron capture or positron emission and it did not come from the same origin as that found in the solar nebula
Where did the carbon dioxide in our atmosphere come from?
At divergent tectonic boundaries where magma is exposed, outgassing due to volcanic activity and also human activity
Where did the Earth’s water come from?
Outgassing from volcanoes (small amount), comets/asteroids (not a primary source though) and purple sulphur bacterial uses sulphur in photosynthesis and produces water
What are the names of the five major regions that divide the Earth’s atmosphere? (closest to Earth to furthest)
Troposphere, stratosphere, mesosphere, thermosphere, exosphere
Why is the Earth’s atmosphere divided up the way it is (ie what is it dependent on)?
How the temperature changes with altitude (pressure)
Do the ‘pauses’ in atmosphere (eg tropopause, stratopause, mesopause) occur above or below the region its named after?
Above
How does temperature relate to altitude in the troposphere?
Temperature decreases with altitude
What percentage of the atmospheric mass is in the troposphere?
75%
How far up does the troposphere go?
7km at the poles to 17km at the equator
How does temperature relate to altitude in the stratosphere (this also has a name)?
The stratospheric inversion means that the temperature starts to increase with altitude
What causes the inversion in the stratosphere?
The ozone layer
After the tropopause, how far up does the stratosphere go up to roughly?
50km above the Earth’s surface
Is the stratosphere stable against convection?
Yes
As altitude increases, does pressure increase or decrease?
Decrease
How does temperature relate to altitude in the mesosphere and what does this cause?
Temperature quickly decreases with altitude, causing strong winds to develop
Which region of our atmosphere do most meteors disintegrate?
In the mesosphere
At what point in the atmosphere is the temperature the lowest and why?
The mesopause because of carbon dioxide radiative cooling
How far up does the mesosphere go roughly?
85km
How does temperature relate to altitude in the thermosphere?
Temperature starts to increase with altitude
What region in the Earth’s atmosphere does the aurora appear and what are they from?
Thermosphere and interactions with nitrogen and oxygen
What is the ionosphere composed of?
Ionised gas with different regions of electron density defined by different radiation penetration
Where is the ionosphere located in terms of the other regions in our atmosphere?
Mostly in the thermosphere but also overlaps with the mesosphere and exosphere
What is the heterosphere?
The part in the atmosphere which is layered by molecular weight and electric charge (gases separate out)
What is the homosphere?
The part in the atmosphere where the composition of the atmosphere is uniform. Turbulent mixing causes this composition to be homogeneous.
Where is the heterosphere and homosphere of the Earth?
The homosphere is from the Earth’s surface up to part way through the thermosphere and then the heterosphere is directly on top of this so a lot of the thermosphere and all of the exosphere
What is the exobase?
The lower boundary of the exosphere and it marks the altitude from which the atmosphere is so rarified (very low pressure) that thermal considerations no longer play a dominant role in the particle motion and the constituents of the atmosphere behave as free particles
How do gas particles act like in the exosphere?
They no longer act like a gas
How is the concentrations of species A written in chemical reactions?
[A]
What is the law of mass action?
The reaction rate in a chemical reaction at a given temperature is proportional to the product of the active masses of the reactants
What is photodissociation also called?
Photolysis or photodecomposition
What is photodissociation?
A chemical reaction which is the interaction of one or more photons with one target molecule and breaks down the molecules
What does the ozone consist of?
oxygen 3
How do we know the ozone layer exists?
If you look at the sun’s spectrum through the Earth’s atmosphere, there’s a gap in the UV portion of the spectrum
What is the name of the explanation of the ozone layer and how many stages are there to it?
The Chapman mechanism and 4
What is step 1 of the Chapman mechanism?
High energy photons break dioxygen (molecular oxygen) into two atomic oxygen radicals (atomic oxygen) (this is photodissociation)
What is step 2 of the Chapman mechanism?
Atomic oxygen binds with a dioxygen (molecular oxygen) to form ozone and also includes some other stable air molecule (like dinitrogen) to take some excess KE but doesn’t change
Which part of the Chapman mechanism contributes to the heating of the stratosphere where the ozone is?
The second stage
What is step 3 of the Chapman mechanism?
A low energy photon breaks up the ozone into atomic and molecular oxygen (photodissociation again I think)
What is step 4 of the Chapman mechanism?
Atomic oxygen and ozone react to make molecular oxygen (2 of them) and this is metastable
What do we start and end with in the Chapman mechanism?
Molecular oxygen
What does the ozone layer block and what do these things do if it could get through?
UVC and most UVB radiation, and these cause damage to DNA
Does UVA make it past the ozone layer and what does this do to us?
Yes and it damages collagen
(Chapman Mechanism) What are the symbols of the reaction rate of C1, reaction rate coefficient for C2, reaction rate for C3 and reaction rate coefficient for C4?
J2, K12, J3 and K13
Why are the reaction rates/ reaction rate coefficient named with numbers the way they are for the Chapman mechanism?
The number represents the type of oxygen of the reactant side (eg 1 for atomic oxygen) and there are multiple numbers if there is multiple oxygen types on the reactant side
Do the photodissociation rates in the Chapman mechanism (J2 and J3 in steps 1 and 3) increase or decrease as you decrease altitude?
Decrease
The catalyst to the second step of the Chapman mechanism depends of the density of air, how does this change with altitude?
It increases as you decrease altitude
The ozone layer forms when the decrease in photodissociation meets what?
Increase in density when you head to the ground
Who is responsible for a lot of the destruction of the ozone?
Thomas Midgley Jr
What did Midgley do that destroyed the ozone?
Developed Freon, a type of CFC, as a refrigerant and this destroys the ozone
How do CFCs destroy the ozone?
They react with high energy photons to make a free chlorine, which acts as a catalyst for ozone destruction and doesn’t get absorbed in the reaction so continues to damage
How long does free chlorine hang around in the upper atmosphere before dropping down and dissolving into water?
2 years
What year is the ozone expected to be naturally replenished?
2065
What is the ideal gas law?
PV=nRT=N(k_b)(N_A)T
What is the pressure exerted by a gas on a box that contains it? (in terms of density and velocity)
1/3 times the density times the expectation of the squared velocity
What are all the ways an atmosphere can escape from a planet?
Jeans escape (thermal), hydrodynamic escape, solar wind pressure, photochemical, magnetospheric wind, charge exchange
What is escape velocity?
The speed something needs to reach to get to infinity and leave the gravitational pull entirely
What speeds do the particles need to be to avoid Jeans escape and make the atmosphere stable? (average speeds determined by temperature)
A lot smaller than the escape velocity
What factors are depended on to know whether a planet will lose its atmosphere?
The mass and radius of the planet, the mass of the particles and the temperature
The pressure for a column of air is just due to what?
The weight of the air
What is hydrostatic equilibrium?
The air is not moving because the force pulling down from gravity is balanced by the pressure-gradient force pushing up
What is the atmospheric scale height?
The length scale of the atmosphere where pressure and density changes by e
What is the lapse rate?
The rate of decrease in temperature with altitude
What is the equation for lapse rate?
Minus the derivative of temperature wrt altitude
What is the dry lapse rate?
The air is not saturated with water vapour
What is the moist lapse rate?
The air is saturated
What is the environmental lapse rate?
The local specific lapse rate
What equation holds for hydrostatic equilibrium when we assume the only force acting is gravity?
the derivative of pressure wrt to altitude is minus the density times gravity
What is an adiabatic process?
A process where no heat or mass is transferred to the surroundings
What is the equation for the dry adiabatic lapse rate?
gravity divided by the isobaric heat capacity (constant pressure)
What is the dry adiabatic lapse rate for Earth?
9.8 K/Km
The adiabatic lapse rate is the largest or smallest positive lapse rate a column of air can have before becoming unstable?
Largest
When the lapse rate is less than the adiabatic lapse rate the atmosphere is stable/unstable and convection will/ won’t occur?
Stable and won’t
What is convection?
The transfer of heat due to the motion of its medium
What is the principal mode of heat transfer in the atmosphere and why?
Convection because it is difference in temperature that cause the air to move
If the lapse rate is stable, what will a displaced parcel of air do?
It will move back to where you took it from
If the lapse rate is neutral (equally to the dry adiabatic lapse rate), what will a displaced parcel of air do?
It will stay where you put it
If the lapse rate is unstable (more than the dry adiabatic lapse rate), what will a displaced parcel of air do?
It will continue to rise on its own
Instead of saying ‘hot air rises’, we can say if a column of air is …. to convection then hot air will rise?
unstable
What is the potential temperature?
It is the temperature a parcel of air would have at a specific pressure if moved adiabatically to that pressure level
What is the environmental lapse rate inversion and what happens to gas particles there?
The point between the stable and unstable lapse rates and gas particles tend to get trapped at inversion, where warmer air is above cold air
What is the latent heat of vaporisation?
The amount of heat required to convert liquid into vapour
On the graph of temp against heat where something goes through all 3 phases, what shoes the energy needed for the separate phase changes?
The length of the plateau region where heat is added but temperature is not raised
What is the saturation temperature of water?
The temperature at a fixed pressure at which the liquid and vapour phases of water coexist
What is the saturation pressure?
At a fixed temp the pressure at which two phases can coexist
What is the dew point?
The temperature at which a sample of air would reach 100% relative humidity and the temperature to which air must be cooled to become saturated with water vapor
The dew point is the point where the rate of evaporation matches what?
The rate of condensation
What are the condensation and evaporation rates functions of?
Condensation - vapour density. Evaporation - temp