Entropy Flashcards
What is true for the Clausius inequality?
the cyclic integral is always less than or equal to zero
What is the Clausius inequality true for?
all cycles, including reversible and irreversible
What can be said about the Clausius integral for a reversible reaction?
equal to zero
What can be said about the Clausius integral for an irreversible reaction?
<0
What are properties?
variables that are not process dependent and depend only on initial and final states.
What is the third law of thermodynamics?
the entropy of a pure crystalline substance at absolute zero temperature is zero
What does the entropy equation become if there are energy losses?
Q+Ef = T
What is the heat transfer for an adiabatic reaction?
Q=0
What is the change in entropy if a process is reversible?
delta s = 0
What is the name for a reversible adiabatic process?
there is constant entropy and it is termed isentropic
What is the increase of entropy principle?
The entropy of an isolated system during a process always increases or in the limiting case of a reversible process, remains constant
What is the performance of thermodynamic systems degraded by?
irreversibilities