Entropy Flashcards
Spontaneity and irreversible change
1
Q
Heat conditions of irreversible spontaneity
A
qrev - q > 0
2
Q
Multiplicity equation
A
W = n^N
3
Q
entropy equation
A
S = kbln(W)
4
Q
change in entropy equation for gases
A
nRln(Vf/Vi)
5
Q
relationship between heat and entropy
A
dS = qrev/T
6
Q
Entropy of reversible reactions
A
dSuni = dSsys + dSsurr = 0
7
Q
change in entropy for a phase change
A
dSsys = dHtrans/Ttrans
8
Q
entropy and temperature relationship using Cp
A
dS = integral(Cp(T)/T)
9
Q
Entropy (not entropy change) equation
A
S2 = S1 + Sm (standard molar entropy)