Entropy Flashcards

1
Q

What is Entropy

A

A measure of how spread out or how dispersed the systems ENERGY is

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2
Q

What does W=X^N signify

A

The number of possible arrangements for molecules

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3
Q

What is Ssys = S(final)-S(initial)

A

The change in entropy of a system

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4
Q

What is the equation: ∆Ssys = nR× ln Vfinal/Vinitial used for

A

Change in entropy, used for isothermal expansion or compression of an ideal gas

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5
Q

Why is ∆Ssys = nR× ln Vfinal/Vinitial not used often

A

It is difficult to calculate W

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6
Q

What is W

A

possible arrangements of molecules

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7
Q

Define Standard Entropy S^o

A

The absolute entropy of a system at 1 atm

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8
Q

Which has a greater entropy, a liquid or a gas phase

A

Gas phase:

More possible W and gas occupies a greater volume

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9
Q

Which h as a greater entropy, a solid or liquid phase

A

Liquid phase

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10
Q

What is a monatomic species

A

An element that consists of a single atom

the noble gases

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11
Q

For two substances in the same phase, and with similar molar masses, which substance has the greater standard entropy

A

The substance with more complex molecular structure

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12
Q

For two monatomic species, which one has the higher entropy

A

The one with the greater molar mass

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13
Q

In cases where an element exists in two or more allotropic forms, which form has the greatest entropy

A

The form in which the atoms are more mobile

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14
Q

What is ∆S^orxn = S^o(products) – S^o(reactnats)

A

The change in entropy of a system

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15
Q

if Delta H is positive

A

endothermic reaction

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16
Q

If Delta H is negative

A

exothermic reaction

17
Q

Does a negative Delta H mean spontaneity

A

It favors spontaneity but the sign alone is insufficient to predict spontaneity in every circumstance.