Enthalpy Changes Flashcards
What is the definition of an Enthalpy change?
A measure of the heat given out or taken in during a process
Why is it easier to use Enthalpy change as opposed to energy change?
Because Enthalpy allows for expansion of objects when they’re heated
The volume of the object must be fixed to measure energy change
What is an endothermic reaction?
A reaction that takes in heat energy so has a positive Enthalpy change
The surroundings will be cooler
What is an exothermic reaction?
A reaction which gives out heat energy
It will have a negative Enthalpy change
The surroundings will be warmer
What is the activation energy?
The energy required to break bonds in the reaction
What are the standard conditions?
100 kPa
273K
How can you convert degrees C to K?
Add 273
What is the Enthalpy change of reaction?
The energy change associated with a given reaction
What is the Enthalpy change of formation?
The energy change that takes place when 1 mole of a compound is formed from its constituent elements in their standard state under standard conditions.
What is the Enthalpy change of combustion?
The energy change that takes place when 1 mole of substance is completely combusted.
What is the Enthalpy change of neutralisation?
The energy change associated with the formation of one mole of water from a neutralisation reaction.
What is the energy change when bonds are broken?
Endothermic,+, energy is taken in
What is the energy change when bonds are made?
Exothermic,-, this gives out energy
How can you calculate Enthalpy change for a reaction using bond enthalpies?
The sum of bond enthalpies of reactants - the sum of bond enthalpies of products
What does Hess’ law state?
The Enthalpy change in a chemical reaction is independent of the route it takes