Enthalpy Changes Flashcards

1
Q

What is the definition of an Enthalpy change?

A

A measure of the heat given out or taken in during a process

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2
Q

Why is it easier to use Enthalpy change as opposed to energy change?

A

Because Enthalpy allows for expansion of objects when they’re heated
The volume of the object must be fixed to measure energy change

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3
Q

What is an endothermic reaction?

A

A reaction that takes in heat energy so has a positive Enthalpy change
The surroundings will be cooler

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4
Q

What is an exothermic reaction?

A

A reaction which gives out heat energy
It will have a negative Enthalpy change
The surroundings will be warmer

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5
Q

What is the activation energy?

A

The energy required to break bonds in the reaction

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6
Q

What are the standard conditions?

A

100 kPa

273K

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7
Q

How can you convert degrees C to K?

A

Add 273

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8
Q

What is the Enthalpy change of reaction?

A

The energy change associated with a given reaction

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9
Q

What is the Enthalpy change of formation?

A

The energy change that takes place when 1 mole of a compound is formed from its constituent elements in their standard state under standard conditions.

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10
Q

What is the Enthalpy change of combustion?

A

The energy change that takes place when 1 mole of substance is completely combusted.

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11
Q

What is the Enthalpy change of neutralisation?

A

The energy change associated with the formation of one mole of water from a neutralisation reaction.

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12
Q

What is the energy change when bonds are broken?

A

Endothermic,+, energy is taken in

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13
Q

What is the energy change when bonds are made?

A

Exothermic,-, this gives out energy

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14
Q

How can you calculate Enthalpy change for a reaction using bond enthalpies?

A

The sum of bond enthalpies of reactants - the sum of bond enthalpies of products

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15
Q

What does Hess’ law state?

A

The Enthalpy change in a chemical reaction is independent of the route it takes

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16
Q

What are Enthalpy cycles?

A

Cycles which show alternative routes between reactants and products

17
Q

What is a homogeneous catalyst?

A

A catalyst for a reaction that’s in the same phase as the reactants eg . Liquid catalyst mixed with liquid reactants

18
Q

What is a heterogeneous catalyst?

A

A catalyst for a reaction that’s in a different phase to the reactants or a different liquid layer (immiscible liquid)

19
Q

How does a catalyst work?

A

Lowers the activation energy by providing an alternative route for the reaction to follow