enthalpy and entropy Flashcards
lattice enthalpy
the enthalpy change which accompanies the formation of one mole of ionic compound from its gaseous ions under standard conditions
enthalpy change of formation
the enthalpy change that takes place when one mole of a compound is formed from its elements under standard conditions with all its reactants and products in their standard states
enthalpy change of atomisation
the enthalpy change that takes place for the formation of one mole of gaseous atoms from the elements in its standard state under standard conditions
first ionisation energy
the enthalpy change required to remove one electron from each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions
first electron affinity
the enthalpy change that takes place when one electron is added to each atom in one mole of gaseous atoms to form one mole of gaseous 1- ions
why are second electron affinities endothermic?
a second electron is being gained by a negative ion, which repels the electron away. so energy must be put into force the negatively-charged electron onto the negative ion
enthalpy change of hydration
the enthalpy change which accompanies the formation of 1 mole of aqueous ions from 1 mole of its gaseous ions under standard conditons
enthalpy change of solution
the enthalpy change that takes place when one mole of solute dissolves in a solvent