Enthalpy Flashcards

1
Q

What is bond dissociation enthalpy?

A

Energy required to break a covalent bond between species in a gaseous state

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2
Q

Why is mean bond enthalpy used?

A

The same bond may have different bond enthalpies in different molecules

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3
Q

What are the steps in calculating mean bond enthalpies

A
  1. Draw out chemical drawing
  2. Circle bonds broken and bonds formed
  3. Add together bonds broken and then
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4
Q

Explain the difference between heat and temperature

A

Heat is mass x energy

Temperature is the average kinetic energy of particles

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5
Q

What is specific heat capacity?

What units is specific heat capacity measured in?

A

The amount of heat needed to raise 1g of substance by 1k

Joules per kelvin jg-1 k-1

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6
Q

What’s the specific heat capacity of water?

A

4.2 jg-1 k-1

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7
Q

What is the formula for enthalpy change?

A

Enthalpy change =mass of substance x specific heat capacity x temperature change

Q=m x c x 🔺t

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8
Q

What does an exothermic reaction do?

Is delta h positive or negative?

A

Gives out energy

Negative

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9
Q

What does an endothermic reaction do?

Is delta h positive or negative?

A

Absorbs energy

Positive

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10
Q

Are oxidation reactions usually exothermic or endothermic?

A

Exothermic

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11
Q

Breaking bonds is….

Making bonds is…

A

Endothermic

Exothermic

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12
Q

Mean bond enthalpies are always

A

Positive

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13
Q

What is the standard enthalpy of formation.

A

When 1mol of a compound is formed from standard elements in their standard states

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14
Q

?What is standard enthalpy of combustion?

A

When 1 mol of substance is completely burned in o2 under standard conditions

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15
Q

Describe step by step how to an enthalpy change calculation

A

Work out enthalpy change by using q=mc🔺t formula

Divide answer in jules by 1000 to get kJ

Work out how many moles are in solution by using standard molar formula

Then divide number of kJ by moms to get answer

If question tells you the reaction is exothermic make sure to put a negative sign before your answer

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16
Q

Describe how to do a naturalisation reaction step by step

A

First, enthaply change calculation using q=mc🔺t

Then divide by 1000 to give kJ

Then work out the amount of moms from the concentration triangle

Then divide kJ by moles

Ensure there is a negative symbol before if it is an exothermic reaction