Enthalpy Flashcards
What is bond dissociation enthalpy?
Energy required to break a covalent bond between species in a gaseous state
Why is mean bond enthalpy used?
The same bond may have different bond enthalpies in different molecules
What are the steps in calculating mean bond enthalpies
- Draw out chemical drawing
- Circle bonds broken and bonds formed
- Add together bonds broken and then
Explain the difference between heat and temperature
Heat is mass x energy
Temperature is the average kinetic energy of particles
What is specific heat capacity?
What units is specific heat capacity measured in?
The amount of heat needed to raise 1g of substance by 1k
Joules per kelvin jg-1 k-1
What’s the specific heat capacity of water?
4.2 jg-1 k-1
What is the formula for enthalpy change?
Enthalpy change =mass of substance x specific heat capacity x temperature change
Q=m x c x 🔺t
What does an exothermic reaction do?
Is delta h positive or negative?
Gives out energy
Negative
What does an endothermic reaction do?
Is delta h positive or negative?
Absorbs energy
Positive
Are oxidation reactions usually exothermic or endothermic?
Exothermic
Breaking bonds is….
Making bonds is…
Endothermic
Exothermic
Mean bond enthalpies are always
Positive
What is the standard enthalpy of formation.
When 1mol of a compound is formed from standard elements in their standard states
?What is standard enthalpy of combustion?
When 1 mol of substance is completely burned in o2 under standard conditions
Describe step by step how to an enthalpy change calculation
Work out enthalpy change by using q=mc🔺t formula
Divide answer in jules by 1000 to get kJ
Work out how many moles are in solution by using standard molar formula
Then divide number of kJ by moms to get answer
If question tells you the reaction is exothermic make sure to put a negative sign before your answer