Enthalpy Flashcards

1
Q

what is the enthalpy change

A

the heat change in a reaction at constant pressure

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2
Q

what are the standard conditons for enthalpy change

A

100kPA pressure
298K temperature

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3
Q

what does the Ø indicate

A

substance was in standard state under standard conditions

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4
Q

if a reaction absorbs heat energy from the surrounds what type of reaction is it

A

endothermic > heat ENters the reaction

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5
Q

if heat energy exits a reaction into the surroundings what type of reaction is it

A

exothermic

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6
Q

is breaking of bonds an exothermic or endothermic reaction

A

breaking of bonds is endothermic because energy is absorbed

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7
Q

is the formation of bonds and exothermic or endothermic

A

exothermic because energy is released when bonds are formed

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8
Q

what is mean bond enthalpy

A

the total bond enthalpy / number of bonds
(of same type)

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9
Q

formula for enthalpy change

A

total energy to break bonds - total energy released forming bonds

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10
Q

what is calorimetry used for

A

to work out enthalpy change of combustion

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11
Q

what is the difference between enthalpy change and energy transferrred

A

enthalpy change is kj per mole
energy transferrred is kj

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12
Q

what equation is used to work out energy from acalorimetry experiment

A

q = mc(delta)T

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13
Q

outline step by step how to work out enthalpy change with the calorimetry experiment / q=mc(delta)T

A
  1. work out energy transferred with q=mc(delta)T
  2. work out moles of the substance > mass/MR
  3. work out enthalpy > q / moles
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14
Q

how do you work out energy from calorimetry experiment of SOLUTIONS

A
  1. use q=mc(delta)T > add up masses of both substances
  2. work out moles > conc X vol (convert to dm3)
  3. work out enthalpy > q/moles
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15
Q

how do you determine if the energy transferred value from calorimetry should be a negative or not

A
  • exothermic reaction > negative
  • endothermic reaction > positive
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16
Q

what is Hess’s law

A

the total enthalpy change of a reaction is indepant of the route taken

17
Q

what are the two types of Hess’s cycle

A

formation (deltafH)
combustion (deltacH)

18
Q

how do you determine whether to draw a formation cycle or combustion cycle

A

dependant on the data provided