Energy, elements, atoms and molecules Flashcards

1
Q

What is Avogadro’s constant?

A

number of protons per gram (6.02 x10^23)

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2
Q

Concentration of hydrogen ions in water

A

the concentration of hydrogen ions in water is 1x10^-7

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3
Q

Define anabolism

A

A sequence of chemical reactions that synthesizes molecules from smaller units

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4
Q

Describe the bonding of a water molecule

A

In a water molecule, a covalent bond forms as the two hydrogen atoms share an electron with the oxygen. These additional two electrons allow oxygen to fill its 2p orbitals making it more stable. The covalent bonds in water are single and polar. Because oxygen is more electronegative than hydrogen, the region around oxygen has a partial negative charge and the region near the two hydrogen atoms has a partial positive charge allowing the formation of hydrogen bonds with other polar molecules.

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5
Q

pH equation

A

pH = -log [H + ]

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6
Q

Examples of kinetic energy

A

movement and heat

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7
Q

Define: Atom

A

Smallest unit of matter which still retains the properties of an element; made of subatomic particles (Protons and neutrons in nucleus and electrons in clouds around the nucleus)

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8
Q

Define: Catabolism

A

Breaking down complex molecules into smaller ones

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9
Q

Define: Compound

A

Substance consisting of two or more elements in a fixed ratio

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10
Q

Define: Covalent bonds

A

Sharing of electrons by two atoms: polar (not equal sharing) eg. Water or non-polar (equal sharing). Strong around 400 kJ/mol

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11
Q

Define: Electronegativity

A

the tendency of an atom to attract an electron

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12
Q

Define: Element

A

A substance which cannot be broken down to other substances by chemical reactions.

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13
Q

Define: Heat of vapourisation

A

Energy to convert 1g of water from liquid to gas at 25°C

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14
Q

Define: Hydrogen bonds

A

Molecules with polar bonds; are weak compared to ionic/covalent (10-20 kJ/mol) but are strong when together. Hold together the structure of DNA

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15
Q

Define: Ionic bonds

A

Form between two very different atoms in attraction for the valence electrons come together; for a crystal. Very strong 700kJ/mol

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16
Q

Define: Isotope

A

Different mass number of an element but same atomic number ; Number of neutrons have no effect on the chemical properties so are chemically identical hence are the same element but has different masses

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17
Q

Define: Metabolism

A

The sum of the chemical reactions that take place within each cell of a living organism; provide energy for all vital reactions

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18
Q

What is molarity or M?

A

a unit to measure concentration (moles of solute per litre of solution).

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19
Q

Define: Moles

A

a unit defined as the number of atoms within 12g of carbon-12 (6.02 x10 23 )

20
Q

Define: Orbitals

A

Contain no more than 2 electrons, more stable when filled than unfilled. Elements ‘try’ to lose/ gain electrons in order to obtain filled orbitals

21
Q

Define: Polarity

A

Caused by differences in electronegativity of atoms within a molecule; allows interaction and bonding eg. Hydrogen bonding

22
Q

Define potential energy

A

Energy possessed because of a position eg.chemical energy

23
Q

What are valence electrons?

A

Directly involved in reactions; form bonds

24
Q

Define van der waal’s forces

A

Very weak (0.5kJ/mol), short range, collectively strong. The movement and position of the electrons cause an interaction between electron clouds

25
What is the equation for pH?
pH = -log [H +
26
Examples of kinetic energy
movement and heat
27
How many elements are essential to life?
25 essential elements
28
How many naturally occuring elements are there?
92; each have a unique one or two letter symbol
29
How much do electrons weigh?
1/2000 of a Dalton
30
How much do sub-atomic particles in the nucleus weigh (protons and neutrons)?
1.66x10 -24 g or a Dalton
31
Strength of covalent bonds
Strong around 400 kJ/mol
32
Strength of hydrogen bonds
Weak compared to ionic/covalent (10-20 kJ/mol) but are strong when together
33
Strength of ionic bonds
Very strong 700kJ/mol
34
Strength of van der waal's forces
Very weak (0.5kJ/mol), short range, collectively strong.
35
What elements make up the majority of the remaining weight of organisms (4%)?
Phosphorus, sulphur, calcium and potassium (+ traces of iron and iodine)
36
What four elements make up 96% of living matter?
Carbon, oxygen, nitrogen and hydrogen
37
What happens if a person is deficient in iodine?
Iodine is used in the thyroid gland. If deficient, more hormone is produced leading to the thyroid gland swelling.
38
What is atomic mass?
Sum of masses of all components (e,n and p) in Daltons however electrons are negligible unless in extremely accurate work
39
What is the atomic number?
Number of protons in the atom
40
How to work out the number of neutrons?
Atomic mass - atomic number
41
What is the main use for calcium in the body?
Bones and teeth
42
What is the main use for iron in the body?
haemoglobin
43
what is the main use for phosphorus in the body?
DNA backbone, cell membranes
44
What is the main use for sulphur in the body?
amino acids methionine and cytosine: disulphide crossbridge
45
What is the shape of a P orbital?
three orbitals (so 6e); dumbbell shapes on the x,y and z axis
46
What is the shape of an S orbital?
Spherical shape