Energy changes Flashcards
What happens in an exothermic reaction?
Heat is given out - an exothermic reaction transfers energy to the surroundings, this is shown by a rise in temperature
give an example of exothermic reaction:
- combustion
- neutralisation
- many oxidation reactions
Give an example of an exothermic reaction being used in day-to-day situations:
- some hand warmers
- self heating cans of hot chocolate and coffee
What happens in an endothermic reaction?
Heat is taken in - an endothermic reaction takes in energy from the surroundings. it is shown by a fall in temperature
give an example of an endothermic reaction:
- reaction between citric acid and sodium hydrogen-carbonate
- thermal decomposition
give an example of an endothermic reaction being used in day-to-day situations:
- sports injury packs
What does an endothermic reaction profile look like?
- the products are at a higher energy than the reactants
- the difference in heat represents the overall energy change during the reaction (energy taken in) per mole
what does an exothermic reaction profile look like?
- the products are at a lower energy than the reactants.
- the difference in height is the energy change (energy given out) per mole
- the initial rise in energy represents the activation energy
what type of reaction is bond breaking?
endothermic - energy must be supplied to break the existing bonds
what type of reaction is bond formation?
exothermic - energy is released when new bonds are formed
how to calculate overall energy change?
sum of all energies needed to break bonds in reactants - energy released when the new bonds are formed in products
how does an electrochemical cell work?
1) an electrochemical cell is a system made of 2 different electrodes in contact with an electrolyte.
2) the electrolyte is a liquid that contains ions which react with the electrodes
3) the chemical reactions set up a charge difference between the electrodes
4) if the electrodes are then connected by a wire, the charge can flow and electricity is produced
What does the voltage of a cell depend on?
- type of electrodes
- the bigger the difference in reactivity of the electrodes, the bigger the voltage
- the electrolyte used
what happens in non-rechargeable batteries?
the chemical reactions are irreversible so over time the reacting particles get used up and turned into products of the reaction. Once any of the reactants are used up, the battery cannot be used as the reaction cannot happen
What is a fuel cell?
An electrical cell that is supplied with a fuel and oxygen (or air)