Energetics Flashcards
What is a limiting reagent?
a reactant that runs out first AND decides the amount of products.
Endothermic reactions have…
Positive enthalpy charge
Exothermic reactions have…
Negative enthalpy charge
What are the standard conditions for reactions?
100kPa
298K
Define mean bond enthalpy
THE ENTHALPY CHANGE WHEN ONE MOLE of covalent bonds are broken, averaged over a range of compounds. (always a positive value).
Define standard enthalpy change of reaction.
THE ENTHALPY CHANGE WHEN a reaction occurs in the molar quantities shown in the balanced chemical equation under standard conditions.
Define standard enthalpy change of formation.
THE ENTHALPY CHANGE WHEN ONE MOLE OF a substance is formed from its elements with reactants and products in their standard states under standard conditions.
Define standard enthalpy change of combustion.
THE ENTHALPY CHANGE WHEN ONE MOLE OF substance is completely burnt in oxygen under standard conditions in standard states.
q=mc^T
q= energy transferred (to the substance changing temp) (J)
m= mass of the substance (changing temp) (g)
c= specific heat capacity (of substance changing temp)
^T= change in temp
,
Define Hess’ Law.
The total enthalpy change for a chemical reaction is independent of the route taken.
^rH equation
^rH = (the sum of the bond enthalpy of reactants) - (the sum of the bond enthalpies in products)