Eletromagnetic Radiation And Atomic Spectra Flashcards

1
Q

Describe Electromagnetic radiation

A

Electromagnetic radiation can be described in terms of waves and characterised in terms of wavelength and/or frequency.

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2
Q

Describe the relationship of frequency and wavelength in terms of an equation

A

The relationship between these quantities is given by c = f x(lambda)

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3
Q

Describe how different types of radiation are arranged

A

The different types of radiation arranged in order of wavelength is
known as the electromagnetic spectrum

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4
Q

How are wavelengths of visible light expressed

A

In (nm)

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5
Q

How can electromagnetic radiation be described in terms of waves and particales

A

Electromagnetic radiation can be described as a wave (has a wavelength and frequency), and as a particle, and is said to have a dual nature.

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6
Q

Describe what happens when electromagnetic radiation is emitted or absorbed

A

When electromagnetic radiation is absorbed or emitted by matter it behaves like a stream of particles. These particles are known as photons.

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7
Q

Describe what a photon carries

A

A photon carries quantised energy proportional to the frequency of radiation.

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8
Q

Describe what happens to a substance when a photon is absorbed or emitted

A

When a photon is absorbed or emitted, energy is gained or lost by electrons within the substance.

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9
Q

Equation of energy associated with a single photon is

A

The energy associated with a single photon is given by:
E=hf orE=hc/(lambda)

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10
Q

The energy associated with one mole of photons is given by:

A

The energy associated with one mole of photons is given by:
E=Lhf orE=Lhc/(lambda)

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11
Q

Describe what Avogadro’s constant is and its symbol

A

L is Avogadro’s constant and is the number of formula units in one mole of the substance. (Formula units can be atoms, molecules or groups of ions, depending on the type of bonding present.)

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12
Q

Describe the orientation of electrons when energy is transferred to atoms

A

When energy is transferred to atoms, electrons within the atoms may be promoted to higher energy levels

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13
Q

Describe when an atom emits a photon of light and what happens after

A

An atom emits a photon of light energy when an excited electron moves from a higher energy level to a lower energy level

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14
Q

Describe how a spectrum is produced and how this shows evidence for energy levels.

A

The light energy emitted by an atom produces a spectrum that is made up of a series of lines at discrete (quantised) energy levels. This provides direct evidence for the existence of these energy levels.

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15
Q

Describe how absorption and emission spectra can be used for element

A

Each element in a sample produces characteristic absorption and emission spectra. These spectra can be used to identify and quantify the element.

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16
Q

Describe absorption spectroscopy

A

In absorption spectroscopy, electromagnetic radiation is directed at an atomised sample. Radiation is absorbed as electrons are promoted to higher energy levels

17
Q

How is an absorption spectra produced

A

An absorption spectrum is produced by measuring how the intensity of absorbed light varies with wavelength.

18
Q

Describe how electrons are excited in emission spectroscopy

A

In emission spectroscopy, high temperatures are used to excite the electrons within atoms.

19
Q

Describe what is emitted as electrons drop to lower energy levels

A

As the electrons drop to lower energy levels, photons are emitted.

20
Q

Describe how an emission spectrum is produced

A

An emission spectrum of a sample is produced by measuring the intensity of light emitted at different wavelengths.

21
Q

Describe how the intensity of light emitted or absorbed relates to an element sample

A

In atomic spectroscopy, the concentration of an element within a sample is related to the intensity of light emitted or absorbed.