Elements Of The sea Flashcards

1
Q

What are the group 7 elements

A

Halogens

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2
Q

As you go down the group, what happens to the thermal stability, physical appearance, states, reactivity, volatility, mp/bp

A
Thermal stability decreases
Becomes darker in colour
Gases to liquids to solids
Reactivity decreases
Becomes less volatile 
Mp/bp increases
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3
Q

What is a reducing agent

A

It’s been oxidised and it reduces another ion

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4
Q

What are spectator ions?

A

Ions that don’t change in a reaction

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5
Q

What is a displacement reaction?

What displaces each other in group 7?

A

When an atom pushes out another atom and takes its place
Chlorine displaces bromine and iodine
Bromine displaces iodine

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6
Q

What are the colours formed when halogens react with silver to form silver halides?
+ when ammonium solution is added?

A

Chlorine - White
Bromine - Cream
Iodine - Pale yellow

Chlorine - clear
Bromine - cloudy/bit clear
Iodine - insoluble

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7
Q

O I L R I G?

A

Oxidation Is Loss Reduction Is Gain

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8
Q

What are oxidation states useful for?

A
  • Naming inorganic compounds
  • Deciding what has been oxidised and what has been reduced
  • identifying the oxidising agents and reducing agents
  • balancing redox reactions
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9
Q

What is the oxidation states for :

  • Element
  • Simple ion
  • Compound
  • Complex compound
A
  • 0
  • the charge on the ion
  • charges add to 0
  • charges add to charge on the compound
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10
Q

What is electrolysis?

A

When electricity is passes through a molten or aqueous ionic compound, the compound is broken down and the process is called electrolysis

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11
Q

What Is reduced at the cathode when there’s a group 1/2 metals present?

A

Hydrogen

2H2O + 2e —> 2OH- + H2

(If other metals then the metal is reduced.)
(Hydrogen if acid)

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12
Q

What is oxidised at the anode if the salt is a halide?

A

Halogen

Oxygen if sulfate or nitrate
(Oxygen is alkali)

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13
Q

Kc - constant

What is the equation?

A

[A]a [B]b

Products
___________
Reactants

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14
Q

Risks of chlorine?

A

Toxic gas
Irritant to eyes, skin, respiratory system
Reacts with lungs to for, HCl which effects the tissues

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15
Q

How is chlorine transported?

A
Uses pressurised tank containers
In liquid to store more
If pressure or temp too high, the tanks has pressure release devices to vent the tank and releases Cl as a gas
The tank if made and lined with steel
Dry so doesn't react with anything
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16
Q

Uses of chlorine

A

Water treatment
Household bleach
Remove stains on clothing

17
Q

What is atom economy and what is the equation?

A

It’s the percentage of reactants that end up in the desired products

Atom economy = Mr of desired product / Mr of reactants x 100

18
Q

How do u make hydrogen halides?

A
HCl = sodium chloride + sulfuric acid as it's not a strong enough reducing agent
HBr = sodium bromide + phosphoric acid as its a strong enough reducing agent to reduce sulfuric acid to sulfur dioxide 
HI = sodium iodide + phosphoric acid as it reduces sulfur dioxide to hydrogen sulfide
19
Q
What happens if:
Pressure increases
Temperature increases
Temperature decreases
Pressure decreases
A

Side with fewer gas moles
Endothermic direction
Exothermic direction
Side with more gas moles

20
Q
If concentrations of :
Reactants increase
Reactants decrease
Products increases
Products decrease
A
The equilibrium moves to the 
Products side
Reactants side
Reactants side
Products side
21
Q

What is the trend in thermal stability and acidity as you go down the group?

A

Thermal stability decreases

HCl HBr HI are very acidic

22
Q

What is the reaction with halogens and ammonia?

A

Glass rid dipped in ammonia solution and put it near halogen and a white cloud of ammonium halide is made.