Electrophilic Addition Reaction 29 Flashcards
Addition of X2
Anti addition with 3membered cyclic structure
Addition of HX follow
Markovikof,antimarkovinikof
Addition of H20
First add H+
Second add h20
.
Addition of X2+ H 20
First add halogen (X)
Second add OH
Addition of mercury is k/as
Oxygen mercuration or demercuration
Addition of B2H6 to alkene is known as
Hydroboration
Alkene+ peroxide
Epoxide
Alkene + KMnO4
Diol
Allylic alkene + cl2 room temperature
Anti addition to alkene
Allylic alkene + Cl2 high temperature
Substitution of allylic hydrogen by cl
Full form of NBS
N bromo succinamide
Order of acidity
Alkane ,alkene,alkyne
With reason
Alkyne>alkene>alkane
Alkyne carbon is sp hybridization so EN of this carbon is more
More acidic H20 ,HOR
H2o
More acidic alkyne ,amine
Alkyne
A stronger acid replace …….
Weaker acid from it’s salt