electrophilic addition Flashcards

1
Q

what type of bond fission is electrophilic addition?

A

heterolytic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

what is the observation for a reaction between bromine water and alkenes?

A

orange to colourless

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

where does the first curly arrow start?

A

C=C bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

where does the first curly arrow move to initially ?

A

the electrophile (delta positive)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

where does the curly arrow move to next?

A

delta negative

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

where does the curly arrow move from and to in the second step?

A

from electrophile with lone pair
to positive carbon

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what is the molecule in the second step called?

A

carbocation intermediate

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

alkene + Br2 —> ?
state the conditions

A

haloalkane
RTP

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

alkene + HBr —> ?
state the conditions

A

haloalkane
RTP

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

alkene + H2O —> ?
state the conditions

A

alcohol
concentrated phosphoric acid
300 degrees
60atm

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

alkene + H2 —> ?
state the conditions

A

alkane
nickel catalyst
150 degrees

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

what is a primary carbocation?

A

carbon attached to 1 alkyl group

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

what is the minor product?

A

product on least stable carbocation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

what is the major product?

A

product on most stable carbocation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

what is the least stable carbocation?

A

primary (attached to 1 C)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly