Electronic Configuration Flashcards

1
Q

What is an Orbital?

A

A region of space where one is likely to find an electron

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2
Q

Name the letters of orbitals

A

S, p, d and f

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3
Q

What does the first energy level consist of?

A

A single S-orbital

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4
Q

What does the second main energy level consist of

A

Single s orbital

Three p orbitals (higher energy)

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5
Q

What does the third main energy level consist of

A

Single s orbital
Three p orbitals
Five d orbitals (higher energy)

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6
Q

How many electrons can a single orbital hold

A

2 electrons only if they have opposite spins

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7
Q

Which elements have different orbital rules?

Plus explanation

A

Chromium and Copper

Because the 4s Orbital is considered to be of lower energy

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8
Q

Rule of first row transition metals

A

For transition metals, the electrons in the 4s orbital are removed before the 3d orbital

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9
Q

Electronic configuration for Calcium (20 electrons)

A

1s^2 2s^2 2p^6 3s^2 3p^6 4s^2

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10
Q

What is ionisation energy?

A

It is the measure of the amount of energy needed to remove an electron from an atom

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11
Q

What is the first ionisation energy?

A

The energy required to remove one mole of electrons from a mole of gaseous atoms

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12
Q

Reason for increasing ionisation energy?

A

Because of increasing number of protons as you go down the periodic table
This means that electrons have a greater pull from the nucleus

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13
Q

Why can some elements have lower ionisation energy?

A

Shielding - the inner shells exerts a shielding effect which lowers the effect of the nuclear pull
Distance

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14
Q

Why do ionisation energy drop for some elements

A

Because the last electron is in a new shell, this increases the distance and the shielding effects the energy as well

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15
Q

Explain a trend in ionisation energies (hint: IE)

A

Successive ionisation energies are always stronger than the previous one
-> this is because the electron is being pulled away from a more positive species

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16
Q

Explain a trend in ionisation energy (hint: shells)

A

Large increases occur when there is a change in shell

-> this is because there is a big decrease in shielding

17
Q

Equation for first ionisation energy

A

X(g) —> X+(g) + e-

18
Q

Equation for second ionisation energy

A

X+(g) —> X^2+(g) + e-

19
Q

Trends in periods

A

Ionisation energy increases across a period

—>this is because the nuclear charge is increasing making it more difficult to remove an electron

20
Q

Trends in groups (group 2)

A

There is a general decrease in ionisation energy going down group 2
—>this is because outer electron is in a main level that gets further from the nucleus