Electrolysis 2 Flashcards

1
Q

What happens during copper sulfate electrolysis

A

1) copper ions CU2+ will go into the electrolyte solution of copper sulfate
2) the CU2+ ions will be attracted to the cathode and pure copper will form

CU2*(aq) + 2E- = CU(s)

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2
Q

when is the purification process complete

A

the purification process is complete when the mass of the cathode is constant

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3
Q

how do you measure the mass of copper formed

A

1) Record the initial mass of the electrodes. the cathode must be clean for the copper to stick
2) use a variable resistor because the current may vary during the process

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4
Q

what’s the equation for change of mass

A

change of mass = final mass - initial mass

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5
Q

why is the electrolysis of aqueous solutions more complex

A

they are more complex as you have to consider the water

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6
Q

what is formed in aqueous sodium chloride ( NaCl )

A

Hydrogen is formed instead of sodium

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7
Q

what does applying electricity across aqueous sodium chloride ( NaCl ) produce

A

produces hydrogen gas at the CATHODE

produces chlorine gas at the ANODE

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8
Q

what are the electrodes made out of when involving aqueous solutions ( NaCl )

A

the electrodes are made out of inert graphite or platinum

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9
Q

in electrolysis of the aqueous solution ( NaCl ) the formation of hydrogen at the cathode can be detected using what

A

a lit splint, a squeaky pop will be heard if hydrogen is present

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10
Q

in electrolysis of the aqueous solutions ( NaCl ) how can you detect the presence of chlorine

A

you can smell it

it turns bleaches the litmus paper

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11
Q

what is produced when dilute sulphuric acid is electrolysed ( H2S04 )

A

Hydrogen is produced from the acid and oxygen in the water

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12
Q

What Is produced at the anode and cathode when electricity is applied with graphite electrodes ( H2304 )

A

Hydrogen gas at CATHODE

Oxygen at ANODE

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13
Q

How can you detect the presence of oxygen at the anode (H2S04)

A

glowing splint, splint will re-ignite/glow in tube if oxygen is present

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14
Q

what is formed when graphite electrodes are used to apply electricity across molten lead bromide (PbBr2)

A

Lead metal at the CATHODE

Bromine at the ANODE

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15
Q

How do you know if lead is present (PbBr2)

A

If a shiny metal forms around the cathode

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16
Q

what is bromine observed as and why (PbBr2)

A

bromine is observed as a brown gas because of the high temperatures reached during the process

17
Q

what is produced when electricity is applied across hydrochloric acid with graphite electrodes (HCL) at the anode and cathode

A

Hydrogen gas at the CATHODE (Metal)

Chlorine gas at the anode (Gas)

18
Q

What are the half equations for the electrolysis of lead bromide (PbBr2)?

A

ANODE: 2Br− → Br2 + 2e−

CATHODE: Pb2+ + 2e− → Pb