electrolysis Flashcards

1
Q

What is electrolysis?

A

The process of using an electric current to drive a non-spontaneous chemical reaction.

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2
Q

True or False: Electrolysis is a spontaneous reaction.

A

False

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3
Q

What is an electrolyte?

A

A substance that conducts electricity when molten or in solution.

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4
Q

In electrolysis, where do positive ions move towards?

A

The negative electrode (cathode).

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5
Q

What is the name of the electrode connected to the positive terminal of the power supply in electrolysis?

A

Anode

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6
Q

What is the purpose of a salt bridge in an electrolytic cell?

A

To maintain electrical neutrality and complete the circuit.

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7
Q

What is the product of electrolysis of water?

A

Hydrogen gas and oxygen gas.

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8
Q

What is the half-reaction that occurs at the anode during the electrolysis of water?

A

2H2O(l) -> O2(g) + 4H+(aq) + 4e-

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9
Q

What is the half-reaction that occurs at the cathode during the electrolysis of water?

A

2H2O(l) + 2e- -> H2(g) + 2OH-(aq)

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10
Q

What is the process called when an ionic substance is broken down into its elements using electricity?

A

Electrolysis

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11
Q

What is the purpose of using an inert electrode in electrolysis?

A

To prevent unwanted side reactions.

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12
Q

What type of electrode is commonly used as the cathode in electrolysis?

A

Platinum

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13
Q

What is the term for the movement of ions towards the electrodes during electrolysis?

A

Electromigration

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14
Q

What is the standard electrode potential for the reduction of water to hydrogen gas at 25°C?

A

0.00 V

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15
Q

What is the standard electrode potential for the oxidation of water to oxygen gas at 25°C?

A

+1.23 V

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16
Q

What is Faraday’s first law of electrolysis?

A

The amount of a substance produced at an electrode during electrolysis is directly proportional to the quantity of electricity passed through the cell.

17
Q

What is Faraday’s second law of electrolysis?

A

The amounts of different substances produced by the same quantity of electricity are in the ratio of their equivalent masses.

18
Q

What is the formula to calculate the charge passed during electrolysis?

A

Q = I x t

19
Q

What is the unit of charge used in the formula Q = I x t?

A

Coulombs (C)

20
Q

What is the formula to calculate the number of moles of a substance produced during electrolysis?

A

n = Q / (z x F)

21
Q

What is the unit of charge used in the formula n = Q / (z x F)?

A

Coulombs (C)

22
Q

What does z represent in the formula n = Q / (z x F)?

A

The number of electrons involved in the reaction.

23
Q

What is the formula for Faraday’s constant (F)?

A

F = 96485 C/mol

24
Q

What is the unit of Faraday’s constant (F)?

A

Coulombs per mole (C/mol)