Electrolysis Flashcards
What is the difference between a galvanic cell and an electrolytic cell?
Galvanic Cell: It uses spontaneous reactions to produce an electric current.
Electrolytic Cell: Uses an electric current to drive non-spontaneous reactions (pumping electrons to force the production of a reaction to happen)
What are the fundamentals of the electrolytic cells?
- reduction occurs at the cathode (red cats)
- electrons are gained at the cathode
- positive ions flow towards the cathode
- the cathode is connected to the negative terminal (electricity is pumped into the negative cathode terminal)
- the strongest oxidant |🔝 reacts with the strongest reactant |🔻
- red cats are sad to be electrocuted.
How do you predict the products of an electrolysis?
- Write down all the reactions that occur at the anode and cathode separately.
- On the electrochemical series the right side is for the anode and the left side is for the cathode.
- For the cathode find the highest reaction (strongest) and for the anode find the lowest reaction present (strongest).
- Choose the strongest oxidant (most positive E value)- this will undergo reduction- will occur at the negative cathode. Choose the strongest reductant ( bottom right hand corner)- most negative E vale, this will undergo oxidation at the positive anode
True or False: Electrolysis converts electrical energy into chemical energy.
True
What are the types of electrodes that can be used in electrolysis cells?
Inert and reactive.
Inert: the electrode doesn’t participate in the reaction.
Reactive: The electrode does participate in the reaction.
What is an electrolyte?
It’s the solution (conducting liquid) that is in the the electrolysis procedure.