Electrochemistry Flashcards
Redox Reaction
reaction where oxidation and reduction occur
Reduction
gaining of electrons
Oxidation
loss of electrons
Oxidizing Agent
takes electrons: the Reductant
Reducing Agent
gives electrons: the Oxident
Work
W, energy required to move an electric charge when there is a difference in potential
Potential Difference
energy, in volts, needed to move 1C of pos charge from the neg point to the pos point
Electric Potential
E, energy needed to bring 1C of positive charge to that point
Standard Potential
E^0, potential for a reaction to reduce where all activities are in unity.
Galvanic Cell
spontaneous reaction (electrons flow from neg to pos), generates electricity. Anode on left.
Electrolytic Cell
non-spontaneous. energy must be added for reaction to proceed
Salt Bridge
used to connect two half’s of a cell if one of the species could dissolve and all react on one end
Standard Hydrogen Electrode
standard value of zero, voltage standard potentials are measured against
Free Energy
delta-G, work done on the surroundings
Spontaneous vs non-spontaneous
Cell is pos.
Cell is neg.