Electrochemistry Flashcards
Point of Electrolysis
- Process of passing an electric current through an electrolyte to decompose it and separate it into its elemental constituents
- Helps extract reactive metals
Electrolyte
- Molten Ionic Binary compound
- Can only conduct electricity which ionic crystal lattice is broken and the ions are free to move around and act as charge carriers to conduct electricity
- Since it is IONIC it only conducts in molten state/aq
Cathode
- Connected to negative terminal
- Attracts cations
- Reduction happens here to become a neutral atom
Anode
- Connected to positive terminal
- Attracts anions
- oxidised here into neutral atom
Flow of electricity in a electrolytic cell
Caused by the movement of electrons from ANODE to CATHODE
Process in an electrolytic Cell
- Anions in electrolyte attracted to anode. It is oxidised, meaning it loses electrons
- These lost electrons from the anode, move to the cathode, forming the electric current
- These electrons help in the process of reduction in the cathode, where the cations are attracted to, to form neutral atoms
Elements of an electrolytic cell
- Power supply
- Electrolyte
- Electrode
What is an electrode
Electrical Conductor
type of charge carriers in inner and outer circuits
Inner - Mobile Ions
Outer - Electrons
Common electrodes, and why? + disadvantages
Graphite
Advantages
1. Good Conductor of Electricity
2. Inert, meaning that it does not take part in the electrolysis reaction
3. High MP
Disadvantages
1. Reacts w O2 to form CO2, and thus might need to be periodically replaced
Platinum
Advantages
1. good Conductor of electricity
2. inert, meaning that it does not take part in the electrolysis reaction
Disadvatnages
1. Low MP compared to graphite Might melt when in contact w molten ionic compound