Electrochemistry Flashcards

1
Q

What are oxidation and reduction?

A

Many chemical reactions involve the transfer of electrons.

Oxidation results in the loss of electrons and reduction involves the gain of electrons. LEO (lose electrons-oxidation) says GER (gain electrons-reduction) is an easy way to memorize the terms.

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2
Q

What is a redox reaction?

A

Often times, chemists call oxidation-reduction reactions, that are occurring at the same time, redox for short.

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3
Q

What are spectator ions?

A

In net ionic equations, cross off entities that exist on both sides of the reaction arrow. These are called spectator ions, as they don’t take part in the chemical reaction.

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4
Q

What are half-reactions?

A

A reaction equation that represents either the loss or gain of electrons is called a half-reaction.

A half-reaction that represents the loss of electrons is called an oxidation half-reaction. A half-reaction that represents the gain of electrons is called a reduction half-reaction. Two half-reactions will make up a total reaction. This is called a reduction-oxidation reaction or redox reaction, for short.

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5
Q

What are reducing and oxidizing agents?

A

A reducing agent gives up electrons to another substance - reduces it.

An oxidizing agent removes electrons from another substance - oxidizes it by gaining electrons.

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6
Q

What are anodes and cathodes?

A

The anode is the electrode where oxidation occurs.

The cathode is the electrode where reduction occurs.

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7
Q

What is a galvanic cell?

A

A galvanic cell, also called a voltaic cell, is a type of electrochemical cell that is capable of producing electric current from the energy released by a redox reaction.

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8
Q

What is electrode potential?

A

In electrochemical cells, the difference in potential between an electrode and its solution is its electrode potential, E.

The electrode potential of a reduction half-reaction is its reduction potential. Conversely, the electrode potential of an oxidation half-reaction is its oxidation potential.

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9
Q

What is an electrode?

A

An electrode is a conductive material that allows the flow of electric current into or out of a medium, typically a solution or a gas.

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10
Q

What is cell potential (Ecell)?

A

Cell potential is the measure of the potential difference (voltage) between the two electrodes of an electrochemical cell. It indicates the ability of a cell to drive an electric current through an external circuit.

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11
Q

What is electrolysis?

A

Electrolysis is a process in which an electric current is used to drive a non-spontaneous chemical reaction. Essentially, it is the use of electricity to cause a chemical change that would not otherwise occur naturally.

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12
Q

What is an electrolytic cell?

A

An electrolytic cell is a type of electrochemical cell that uses an external electric current to drive a non-spontaneous chemical reaction.

Unlike a galvanic cell (or voltaic cell), where a chemical reaction generates an electric current, an electrolytic cell requires energy input to cause the reaction.

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13
Q

What is Faraday’s first law?

A

Faraday’s first law of electrolysis states the mass of a substance produced at an electrode during electrolysis is proportional to the number of moles of electrons transferred at that electrode.

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14
Q

What is 96 500 C / mol e ^ -

A

Faraday constant (F).

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15
Q

What is corrosion?

A

Corrosion is a loss of an electron of metals reacting with water or oxygen.

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16
Q

What is electroplating?

A

Electroplating is one solution to keeping costs down while minimizing corrosion. Essentially, electroplating involves putting a layer of an inactive metal on the surface (where corrosion occurs) of a more active metal.