Elastomers Flashcards
The process of changing the rubber
base product or liquid polymer to a rubber-like material.
Vulcanization/Curing
Classification of Elastomers based on chemical composition
- Polyether
- Polysulfides
- Silicones
a. Addition
b. Condensation
Types of consistency/viscosity for rubber impressions
- Light bodied impression
- Regular/medium bodied
- Heavy bodied
A group of flexible chemical polymers that are either chemically
or physically cross-linked.
Elastomeric Impression Materials
T or F
Elastomeric impression materials can be easily stretched and rapidly recover their original dimensions when applied stresses are released
True
Introduced in Germany in late 1960’s and first elastomer to be developed as impression material.
Polyether
Polyether Base and Catalyst
Base
- polyether polymer
- colloidal silica (filler)
- glycol ether or phthalate
Catalyst
- alkyl aromatic sulfonate
Advantages of polyether
- Fast working and setting time
- Less hydrophobic (better wetting)
- Long shelf life
- Proven accuracy
- Adequate tear strength
Disadvantages of polyether
- Clean but tastes bad
- Slightly more expensive
- Stiffness requires blocking undercuts
First non-aqueous elastomeric impression material often called “rubber” or “rubber base”
Polysulfide
Polysulfide Base and Catalyst
Base
- Lithopone and titanium
dioxide (filler)
- Dibutyl phthalate (plasticizer)
- Sulfur (0.5%)
Catalyst
- Lead dioxide (dark
brown color)
- Oleic and stearic acid
(retarders)
Polysulfide disadvantages
- Requires a custom tray
- Odor (unpleasant)
- Messy and stains
clothes - Second pour is less
accurate - Potential for significant
distortion
It was the first type of silicone impression material, and also known as conventional silicones.
Condensation silicone
supplied as a base paste and a low-viscosity liquid catalyst, a two-paste system, or a two-putty system
Condensation silicone
Condensation silicones advantages
- Adequate working and
setting time - Pleasant odor and no
staining - Adequate tear strength
- Better elastic properties
on removal
Condensation silicone base and catalyst
Base
- Colloidal silica
- Metal oxide (filler)
- Colorants (homogenous
mix)
Catalyst
- Alkyl silicate and organo-tin compounds
Condensation silicones disadvantages
- Poor dimensional
stability - Slightly more expensive
- Putty wash method is
technique sensitive. - Potential for significant
distortion
Frequently called as polyvinyl siloxane, and introduced after condensation silicones.
Addition silicone