Effect of temperature on rate constants Flashcards
1
Q
What is the effect of temperature on rate constants?
A
As temperature increases, the rate increases and the value of K increases
2
Q
Why does increasing temperature, increase the value of K?
A
- Increasing temperature, shifts the boltzmann distribution to the right and increases the proportion of particles that exceeds EA
- As temperature increases, the particles move faster and collide more frequently
- This therefore increases the rate constant due to activation energy
3
Q
How do you rearrange arrhenius equation?
A
Ink = -EA/RT + InA
T = kelvin
R = 8.314
4
Q
How do you determine the activation energy from a graph?
A
Gradient = -EA/R
EA = -Gradient x R
5
Q
How do you calculate A?
A = number of collisions with the correct orientation
A
The Y intercept is InA
Then do the exponential of A
eA
6
Q
How do you plot a graph to find arrhenius equation?
A
ink = Y axis
1/T = X axis