E/Z isomers Flashcards
What are stereoisomers?
Same structural formula but a different arrangement for atoms in 3D space
What are the conditions for a molecule to be an E/Z isomers?
It must contain a C=C bond and it must average two different groups of atoms attached to each carbon in the C=C
Why do alkenes for E/Z isomers?
The C=C bond is unable to rotate
How do you decide the priority group?
The atom directly attached with the highest atomic number. If they are the same, list the atomic numbers one bond further out and the first group with a highest number, is the priority group.
How do you decide the priority group is the first two atoms are the same?
List the atomic numbers one bond further out and the first group with a highest number, is the priority group
What is a Z isomer?
The priority groups are on the same side
What is an E isomer?
Priority groups are on opposite sides of the
What is cis/trans isomerism?
When one of the groups attached to each carbon of the double bond is the same
What is a cis isomer?
The matching groups are both on the same side
What is a tans isomer?
When the matching groups are on opposite sides of