DISTILLATION Flashcards

1
Q

Tendency of a substance to lead a phase

A

Chemical potential

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2
Q

Temp at which a liquid mixture of a given composition begins to vaporize as the temp is increased

A

bubble point

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3
Q

Increase in dew point will result to

A

decrease in temp, increase in pressure

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4
Q

a mixture with an equilibrium vapor of the same composition as the liquid

A

azeotrope

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5
Q

This process involves heating a liquid mixture and then allowing it to expand into a vessel maintained at low pressure

A

Flash distillation

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6
Q

Method of distillation used for the recovery of carotenes, omege 6 and 9

A

Steam distillation

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7
Q

When relative volatility is 1 to 1.2, distillation is _____

A

not economical

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8
Q

Distillation of EtOH -H2O system by adding benzene

A

Keyes Process

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9
Q

Upon adding an external compound, if the resulting ternary system behaves as two system, it is called____\

A

extractive distillation

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10
Q

If the resulting ternanru system behaves as three phase

A

azeotropic distillation

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11
Q

distillation is carried out at a relatively uniform pressure with temp varying from stage to stage

A

isothermal distillation

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12
Q

This method involves the use of enthalpy composition diagram

A

Ponchon Savarit method

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13
Q

This method assumes that there is constant molar flowrate of liquid and vapor phases

A

McCabe Thiele Method

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14
Q

Assumptions in McCabe thiele method

A

Molar heats of vaportization are roughly the same
Heat effects are negligible
-For every mole of vapor condensed, one mole of liquid is vaporized

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15
Q

Relative volatility of the mixture at the azeotropic point where the solution exhibits minimum boiling is

A

Equal to 1

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16
Q

When the molal heat of vaporization of the binary system is very much dependent of concn, the most appropriate to use to determine the no. of ideal stage is

A

Ponchon Savarit method

17
Q

McCabe Thiele method follows what rule

A

Trouton’s rule

18
Q

Another term for stripping

A

Desorption

19
Q

Degrees of freedom associated with distillation of a mixture with C components accdn to Gibbs phase rule

A

C

20
Q

Difference between the number of intensive variables needed to characterize systems at equilibrium and the number of equation that relate these variables

A

Degrees of freedom

21
Q

Relating observable properties with chemical potential

A

fugacity