DISTILLATION Flashcards
Tendency of a substance to lead a phase
Chemical potential
Temp at which a liquid mixture of a given composition begins to vaporize as the temp is increased
bubble point
Increase in dew point will result to
decrease in temp, increase in pressure
a mixture with an equilibrium vapor of the same composition as the liquid
azeotrope
This process involves heating a liquid mixture and then allowing it to expand into a vessel maintained at low pressure
Flash distillation
Method of distillation used for the recovery of carotenes, omege 6 and 9
Steam distillation
When relative volatility is 1 to 1.2, distillation is _____
not economical
Distillation of EtOH -H2O system by adding benzene
Keyes Process
Upon adding an external compound, if the resulting ternary system behaves as two system, it is called____\
extractive distillation
If the resulting ternanru system behaves as three phase
azeotropic distillation
distillation is carried out at a relatively uniform pressure with temp varying from stage to stage
isothermal distillation
This method involves the use of enthalpy composition diagram
Ponchon Savarit method
This method assumes that there is constant molar flowrate of liquid and vapor phases
McCabe Thiele Method
Assumptions in McCabe thiele method
Molar heats of vaportization are roughly the same
Heat effects are negligible
-For every mole of vapor condensed, one mole of liquid is vaporized
Relative volatility of the mixture at the azeotropic point where the solution exhibits minimum boiling is
Equal to 1