Developing Fuels Flashcards

1
Q

Standard enthalpy change of combustion

A

Enthalpy change when one mole of a fuel is burned completely in oxygen under standard conditions

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2
Q

Standard Enthalpy change of formation

A

Enthalpy change when one mole of a compound in its standard state is formed from its elements in their standard states

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3
Q

Enthalpy change of reaction

A

Enthalpy change when molar quantities of reactants stated in the equation react together under standard conditions

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4
Q

Entropy

A

A measure of the number of ways that particles in a substance can be arranged

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5
Q

Exothermic

A

Reaction gives our heat energy to surroundings, delta H is negative

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6
Q

Endothermic

A

Reaction that takes in heat energy from surroundings, delta H is positive

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7
Q

Specific heat capacity

A

The heat energy required to increase the temperature of 1g of a substance by 1K

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8
Q

Standard states

A

Physical states of an element at 298K, 1 atmospheric pressure

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9
Q

Catalytic cracking

A

Thermal decomposition of long chain hydrocarbons into shorter chains, some have double bonds

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10
Q

Fractional distillation

A

Separation of substances with different boiling points (I.e crude oil) by evaporation then condensation at different temperatures

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11
Q

Knocking/ Autoignite

A

When fuel/oxygen mixture ignited without a spark during compression in an engine

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12
Q

Octane number

A

Measure the tendency of petrol mixture to auto ignite after compression (without spark)

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13
Q

Volatility

A

The ease of evaporation of a compound (more volatile means lower boiling point)

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14
Q

Zeolite

A

Mineral containing Al, Si and O that contains pores into which hydrocarbons can fit. Used as catalyst and as molecular sieve in oil refining.

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15
Q

Heterozygous catalyst

A

Catalyst that is in a different physical state to the reactants

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16
Q

Isomerisation

A

Reaction in which one isomer is turned into another (i.e used in oil refinery to convert straight chain to beaches chain alkanes)

17
Q

Reforming

A

Reaction in which straight chain molecules are converted into cyclic aromatic compounds by removal of H2 using Pt catalyst

18
Q

Catalyst poison

A

Substance that is adsorbed strongly to the catalyst surface preventing the adsorption of the usual reactants

19
Q

Biofuel

A

Fuel that is prepared form living raw material (I.e ethanol from cane sugar, carbon neutral)

20
Q

Oxygenate

A

Substances containing oxygen

21
Q

Alcohols

A

Homologous series with functional group -OH

22
Q

Aliphatic

A

Acyclic or cyclic compounds that are non-aromatic (no benzene rings)

23
Q

Alkane

A

Hydrocarbons with general formulae CnH2n+2

24
Q

Arene/Aromatic

A

Cyclic compounds containing rings of delocalised electrons (eg benzene)

25
Q

Ether

A

Compound containing C-O-C group, isomer of alcohol

26
Q

Homologous series

A

A series of compounds with the same general formula, in which each member differs from the next by a CH2 group

27
Q

Isomer

A

Molecules with the same number of each type of atom bonded in a different arrangement

28
Q

Saturated

A

Contains no double cc bonds

29
Q

Unsaturated

A

Contains double CC bonds

30
Q

Addition

A

Reaction in which two molecules bond and no other product is formed

31
Q

Electrophile

A

A molecule or ion that can except a pair of electrons to form a bond to an electron rich atom

32
Q

Addition polymerisation

A

Polymerisation in which small monomers bonded to formal long chain molecules with no other products

33
Q

Carbocation

A

Carbon with a positive charge

34
Q

Co-polymer

A

Polymer found form two different monomers

35
Q

Energy transferred

A

mass of water * SHC of water (4.18h * change in temperature

36
Q

Enthalpy of combustion (equation)

A

Heat energy transferred (j) dived by amount in fuels (moles)

37
Q

Hess’s law

A

The Enthalpy change for a reaction is independent of the route taken from reactants to products, providing the conditions stay the same