Developing Fuels Flashcards
Standard enthalpy change of combustion
Enthalpy change when one mole of a fuel is burned completely in oxygen under standard conditions
Standard Enthalpy change of formation
Enthalpy change when one mole of a compound in its standard state is formed from its elements in their standard states
Enthalpy change of reaction
Enthalpy change when molar quantities of reactants stated in the equation react together under standard conditions
Entropy
A measure of the number of ways that particles in a substance can be arranged
Exothermic
Reaction gives our heat energy to surroundings, delta H is negative
Endothermic
Reaction that takes in heat energy from surroundings, delta H is positive
Specific heat capacity
The heat energy required to increase the temperature of 1g of a substance by 1K
Standard states
Physical states of an element at 298K, 1 atmospheric pressure
Catalytic cracking
Thermal decomposition of long chain hydrocarbons into shorter chains, some have double bonds
Fractional distillation
Separation of substances with different boiling points (I.e crude oil) by evaporation then condensation at different temperatures
Knocking/ Autoignite
When fuel/oxygen mixture ignited without a spark during compression in an engine
Octane number
Measure the tendency of petrol mixture to auto ignite after compression (without spark)
Volatility
The ease of evaporation of a compound (more volatile means lower boiling point)
Zeolite
Mineral containing Al, Si and O that contains pores into which hydrocarbons can fit. Used as catalyst and as molecular sieve in oil refining.
Heterozygous catalyst
Catalyst that is in a different physical state to the reactants