Dental Materials Flashcards
Three Classes of materials
metals
ceramics
polymers
mechanical properties of metal
hard, ductile (bends), strong
bonding of metal
1-3 electrons in their outer shell key in metallic bonds
free mobility of electrons makes them
thermally and electrically conductive
temperature while forming metal effects
the strength of the metal
molten metal leads to
polycrystalline structures (formation of grains)
metal is made to resist
deformation
mixing of metals makes
alloy
what metals make up amalgam
alloy + Hg
Mechanical Properties of ceramic
hard, brittle (shatters), strong
bonding types of ceramics
ionic and covalent (stronger than metallic bonds)
covalent bonds share or donate electrons
share
ionic bonds share or donate electrons
donate/accept
bonding of ceramics crystal wise are
semicrystalline or polycrystalline
ceramics melt at ____ temperatures to form
high
most common ceramics
SiO2
Al2O3
K2O
Mechanical properties of polymers
soft, ductile (bends), weak
bonding type of polymers
covalent bonds
long polymer chains (nonmetallic)
derive strength and properties form entanglement
free radical concept to make polymers
activation
initiation
propagation
termination
direct processing
stable material
rapid setting
room temperature
doesn’t last a long time
metal processing in general terms
high processing temperatures and indirect placement (except amalgam)
ceramic processing in general terms
high processing temperatures and indirect placement (exception: cements)
polymers processing in general terms
lower processing temperatures and direct placement (exception: indirect composites)
- impressions, temp crowns, restorations
Polymerization process Step 1
activation: free radical initiation
Polymerization process Step 2
initiation: free radical combination with monomer unit and double bond opening
Polymerization process Step 3
propagation: chain growth
Polymerization process Step 4
termination
polymerization can be initiated by:
light, heat, chemical mixin
linear polymer cannot become
tangled because no long chain brances
cross linked polymers can become
tangled because long chain branches and therefore mechanically stronger
a composite is
a physical mixture of metals, ceramics, and polymers
goal of composite
to achieve some intermediate properties between two material types
rule of mixtures states
knowing phases present in strucutres of materials makes it possible to predict overall properties of combination
role of fillers
chemically bond to resin phase to improve properties
- increase filler volume
- increase strength, modulus, viscosity, surface roughness
- decrease shrinkage
thermal expansion coefficient of tooth
9-11
thermal expansion coefficient of amalgam
25
thermal expansion coefficient of compostie
28-35
ideally you want a composite that is close to the
tooth coefficient
materials that are not insulators can spread temperature too fast and it will
cause pain
composites have low …. and therefore dont need…
low thermal conductivity and do not need a base
metals do or do not need a base in their composition
do
color is defined in a
3D coordinate system
hue
wavelength (color)
value
intensity and brightness (white vs black)
chroma
purity and concentration (density/intensity of color)
metamerism**
two colors look the same under one light but then look different under another light
mercury issues with amalgam
patients don’t like color/mercury
proper disposal of toxic material
some patients have reaction to amalgam
operator issues with amalgam
controlling substance and removing wet surface
mechanical properties of amalgam
brittle*
higher compressive strength than tensile strength
creep
amalgam has good/poor edge strength
poor
creep of amalgam
solid material moves slowly/deforms permanently under mechincal stress (long term)
amalgam full strength at
1 week (basically same as strength after 24 hours)
galvanic corrosion
between anode and cathode at interproximal contacts
unpolished scratches (secondary anatomy) lead to:
lower pH and oxygen concentration of saliva
chemical corrosion occurs form reaction with
sulfide ions on occlusal surface
pits and scratches that aren’t polished
catch debris and cause corrosion
gamma 1 (y1)
siver mercury
gamma 2 (y2)
tin mercury
Chemical composition
silver- 40-60%
Tin- 27-30
copper- 13-30
zinc- 1%
Classification: High copper
> 12% copper
high copper properties
longevity of restoration (resists deformation)
low creep values
zinc containing properties
facilitatates lathe cut particles
improves corriosion resistance
low copper
original mix (now high copper is used)
elements used in alloying
copper* zinc silver tin (indum, mercury, noble metals)
Setting Reaction Phases
Initial contraction when alloy is absorbing mercury.
Expansion from formation and growth of y1 and y2.
Final absorption of mercury again causes contraction
Starting alloy+ mercury
reaction phase
Y steps
Y1 and y2 form initially (step 1), then Y2 dissapears (step 2)
heat treatment of alloy
eliminates nonuniformity that exist in both lathe cut and spherical
- allows companies to control setting times of materials
lathe cut
machined from cast ignot