dental luting agents Flashcards
3 luting agent type examples
dental cement
composite resin
GIC
give 5 good properties of a luting agent
low viscosity
radiopacity - to see marginal breakdown
marginal seal - ideal if bonds to tooth
biocompatible - non toxic, no heat on set
easy to use
ideal film thickness
as thin as possible - 25 microns or less
how can a luting agent be cariostatic
antibacterial
fluoride releasing
4 ideal mechanical properties of dental luting agent
high compressive strength
YM similar to tooth
high hardness
high tensile strength
two examples of dental cement
zinc phosphate
zinc polycarboxylate
what reactions take place when mixing the powder and liquid of zinc phosphate
initial acid base reaction
phosphoric acid and zinc oxide
followed by hydration reaction to produce crystallised phosphate matrix (hopiete)
benefits of zinc phosphate
cheap
easy to use
what component of zinc phosphate gives white colour
magnesium dioxide
what acid is used for zinc phosphate cement
50% phosphoric acid
function of aluminium oxide in zinc phosphate cement
prevents crystallisation leading to amorphous glassy matrix of acid salt surrounding unreacted ZnO
3 negatives of zinc phosphate cement
low initial pH - plural irritation
not adhesive to tooth
not cariostatic
what is the difference between zinc phosphate and zinc polycarboxylate
phosphoric acid is replaced by poly acrylic acid
3 advantages of zinc polycarboxylate
bonds to tooth
cheap
low pH but returns neutral more quickly than zinc phosphate
3 disadvantages of zinc polycarboxylate
difficult to mix
soluble in low pH
lower compressive strength than zinc
what is the difference between GI luting cement and GI filling material
particle size of glass - cement is less than 29 micrometers to allow suitable film thickeness
what type of reaction takes place in GI cement
acid base between acid and glass
acid - poly acid mixture of acrylic acid, maleic acid
glass - silicon dioxide and aluminium oxide
how does GI cement bond to tooth
ion exchange with Ca in enamel and dentine
H bonding with collagen in dentine
how does GI bond to the restoration
mechanical - sandblast restoration to allow mechanical adhesion
no chemical bond
3 advantageous properties of GI cement
low shrinkage
self adhesive to tooth substance
fluoride release
what does RMGIC contain that conventional GI does not
hydrophilic monomer HEMA
hydroxyethyl methacrylate
how is HEMA polymerised in RMGIC
light activation
incorporating resin into GIC to make RMGIC improves what properties
setting time is shorter
higher compressive and tensile strength
higher bond strength to tooth
disadvantage of RMGIC
HEMA is cytotoxic - uncured monomer will damage pulp
no bond to indirect restoration
HEMA expands so shouldn’t be used to cement porcelain (crack) or posts (split root)