Dental Ceramics (Christy) Flashcards
Is all porcelain ceramic?
yes, all porcelain is ceramic
Are all ceramics porcelain?
no, all ceramics are not porcelain
What is kaolin?
kaolin is a clay
Kaolin is hydrated X silicate
X - aluminium
Is kaolin opaque?
yes, kaolin is opaque
Dental ceramics need to be X so kaolin is removed and feldspar and silica replace it
X - translucent
What are the components of dental ceramics?
dental ceramics:
<5% = kaolin
12-25% = quartz (silica)
70-80% = feldspar
1% = metal oxides
up to 15% = glass
What is the main difference between decorative and dental ceramics?
the main difference between dental and decorative ceramics is the amount of feldspar
What does feldspar act as?
felddspar acts as a flux
What lowers the fusion and softening temperature of the glass?
feldspar lowers the fusion and softening temperature of glass
What is the lowest fusing component of dental ceramics and flows during firing, forming a solid mass around the other components?
feldspar is the lowest fusing component and flows during firing, forming a solid mass around the other components
What conveys colour to the ceramic?
metal oxides convey colour to the ceramic
What are conventional dental ceramics supplied as?
conventional dental ceramics are supplied as powder
How is the conventional dental ceramic powder made?
conventional dental ceramic powder is made by:
- heating the constituents to a high temperature (>1000°C)
-
cooling rapidly (fritting)
- cooled in water creating cracks and crazing of the ceramic mass
- mill the frit to a fine powder
- add binder, which is often starch
What do feldspathic ceramics form when heated to 1150-1500°C?
when heated to 1150-1500°C, feldspathic ceramics form leucite
What is leucite?
leucite is potassium aluminium silicate
Fabrication of a crown:
- ceramic powder is mixed with X and applied to the die with a brush
- the crown is built up using different porcelains for dentine and enamel
- these are not tooth coloured
- the crown is heated in a furnace to coalesce the powder into ceramic
- heating leads to sintering, which occurs just above the glass transition temperature
- it is when the ceramic particles begin to fuse into a single mass
- during sintering, the glass phase softens and will coalesce
- over time there is controlled diffusion and a solid ceramic mass is formed
X - water
Fabrication of a crown:
- ceramic powder is mixed with water and applied to the die with a brush
- the crown is built up using different X for dentine and enamel
- these are not tooth coloured
- the crown is heated in a furnace to coalesce the powder into ceramic
- heating leads to sintering, which occurs just above the glass transition temperature
- it is when the ceramic particles begin to fuse into a single mass
- during sintering, the glass phase softens and will coalesce
- over time there is controlled diffusion and a solid ceramic mass is formed
X - porcelains
Fabrication of a crown:
- ceramic powder is mixed with water and applied to the die with a brush
- the crown is built up using different porcelains for dentine and enamel
- these are not tooth coloured
- the crown is heated in a furnace to X the powder into ceramic
- heating leads to sintering, which occurs just above the glass transition temperature
- it is when the ceramic particles begin to fuse into a single mass
- during sintering, the glass phase softens and will coalesce
- over time there is controlled diffusion and a solid ceramic mass is formed
X - coalesce
Fabrication of a crown:
- ceramic powder is mixed with water and applied to the die with a brush
- the crown is built up using different porcelains for dentine and enamel
- these are not tooth coloured
- the crown is heated in a furnace to coalesce the powder into ceramic
- heating leads to X, which occurs just above the glass transition temperature
- it is when the ceramic particles begin to fuse into a single mass
- during sintering, the glass phase softens and will coalesce
- over time there is controlled diffusion and a solid ceramic mass is formed
X - sintering
Fabrication of a crown:
- ceramic powder is mixed with water and applied to the die with a brush
- the crown is built up using different porcelains for dentine and enamel
- these are not tooth coloured
- the crown is heated in a furnace to coalesce the powder into ceramic
- heating leads to sintering, which occurs just above the glass transition temperature
- it is when the X particles begin to fuse into a single mass
- during sintering, the glass phase softens and will coalesce
- over time there is controlled diffusion and a solid ceramic mass is formed
X - ceramic
Fabrication of a crown:
- ceramic powder is mixed with water and applied to the die with a brush
- the crown is built up using different porcelains for dentine and enamel
- these are not tooth coloured
- the crown is heated in a furnace to coalesce the powder into ceramic
- heating leads to sintering, which occurs just above the glass transition temperature
- it is when the ceramic particles begin to fuse into a single mass
- during sintering, the glass phase X and will coalesce
- over time there is controlled diffusion and a solid ceramic mass is formed
X - softens
During sintering, how much does the material contract?
during sintering, the material contracts by about 20%
What dental restorative materials have the best aesthetics?
ceramics have the best aesthetic properties of any dental restorative material
Ceramics retain their surface X than other materials
X - better
Ceramics have X staining long term
X - less
What is it known as when light is allowed to pass through a material unchanged?
when light is able to pass through a material, this material is known as transparency
What is it known as when a material allows only some light to pass through (light changes direction as it passes through)?
a material is translucent when it allows some light to pass through (light changes direction as it passes through)
Are conventional dental ceramics chemically stable?
yes, conventional dental ceramics are chemically stable
Conventional dental ceramics are generally X by the wide pH range found in the mouth
X - unaffected
Do conventional dental ceramics take up stain from food/drink?
no, conventional dental ceramics do not take up stain from food/drink
Conventional dental ceramics have good X as there are minimal adverse effects on biologcial tissues
X - biocompatibility
What is the thermal expansion coefficient of conventional dental ceramics similar to?
the thermal expansion coefficient of conventional dental ceramics is similar to dentine
What can be said about the thermal diffusivity of conventional dental ceramics?
conventional dental ceramics have a low thermal diffusivity
Once fully fired, are conventional dental ceramics stable?
yes, once fully fired conventional dental ceramics are very stable
During the fabrication of conventional dental ceramics, what is a problem?
during the fabrication of conventional dental ceramics, shrinkage is a problem
Conventional dental ceramics have a X compressive strength
X - high
Conventional dental ceramics have a X hardness
X - high
Conventional dental ceramics have a high hardness, what can this lead to?
conventional dental ceramics have a high hardness, this can lead to abrasion of the opposing teeth - especially if they are not glazed
Conventional dental ceramics have a very X tensile strength
X - low
Conventional dental ceramics have a very X flexural strength
X - low
Conventional dental ceramics have a very X fracture toughness
X - low
There is a time dependent X in strength in conventional dental ceramics, even in the absence of any applied force
X - decrease
There is a time dependent decrease in strength of conventional dental ceramics, even in the absence of any applied load. What is this probably due to?
there is a time dependent decrease in strength of conventioanl dental ceramics, even in the absence of any applied load. This is probably due to the hydrolysis of Si-O groups within the material, over time in an aqueous environment
Where can fractures initiate in conventional dental ceramics?
fractures can initiate in conventional dental ceramics at surface micro-cracks
Where can conventional feldspathic ceramics be used?
conventional feldspathic ceramics can only be used in low stress areas
Are conventional feldspathic crowns used as anterior or posterior crowns?
conventional feldspathic crowns are used as anterior crowns
The aesthetics of conventional ceramics are good but they need to be X
X - stronger
What are ways that the problems of conventional ceramics are overcome?
overcoming the problems with conventional ceramics:
- produce a strong coping that is resistant to fracture and cover this with the conventional porcelain
- cast or press a block of harder ceramic
- mill a laboratory prepared block of ceramic
What are examples of the different types of cores used for putting porcelain over?
strong copings:
- alumina core
- zirconia core
What is used as a core material in porcelain jacket crowns?
alumina is used as a core material in porcelain jacket crowns
What do alumina particles in alumina cores prevent?
alumina particles in alumina cores prevent cracks propagating
Aluminous porcelain is X and can only be used as a core material
X - opaque
What type of core was used as the first choice crown for anterior teeth for decades and is not strong enough for posterior use?
an alumina core was used as the first choice crown for anterior teeth for decades and is not strong enough for posterior use
Is specialist equipment needed to create an alumina core?
no, specialist equipment is not required to make an alumina core - just a furnace
Increased alumina content X the strength of the alumina core
X - increases
What is the name of the alumina core technique where the core material has an alumina content of around 85%?
In-ceram is the technique when the core material has an alumina content of around 85%
What is the name of the complicated technique (from in-ceram) being described?:
- the ceramic core is formed onto a refractory model
- a fine slurry of alumina is applied to the model
- it is heated to 1120°C for 10 hours
- this is below the glass transition temperature for alumina
- partial sintering occurs
- a porous core is produced
- the core is infiltrated with lanthanum glass at 1100°C
slip casting:
- the ceramic core is formed onto a refractory model
- a fine slurry of alumina is applied to the model
- it is heated to 1120°C for 10 hours
- this is below the glass transition temperature for alumina
- partial sintering occurs
- a porous core is produced
- the core is infiltrated with lanthanum glass at 1100°C
In-ceram-spinel has X (Mg2O4) rather than alumina as its core material
X - spinel
In-ceram-spinel has better X but lower flex strength
X - aesthetics
What is the name of the technique which creates a pure alumina core that is >99% pure?
Procera creates a pure alumina core which is >99% pure
What region are In-Ceram and Procera core types suitable for?
In-Ceram and Procera core types are suitable for single posterior crowns
Are In-Ceram or Procera crowns used as a bridge material?
no, In-Ceram and Procera cores are not often used as a bridge material
What is probably the most popular ceramic core material?
zirconia is probably the most popular ceramic core material
What can be said about the hardness of zirconia?
zirconia is very hard
Zirconia powder does not sinter unless heated to over X°C
X - 1600
What is the zirconia used in dentistry?
the zirconia used in dentistry is yttria-stabilised zirconia
Pure zirconia can X on cooling
X - crack
Normal zirconia is a X crystal at room temperature
X - monoclinic
Yttria is a X crystal structure
X - tetragonal
If a crack begins in zirconia when the stress at the crack tip reaches a critical level, the crystal structure transforms to the X structure. This causes a slight expansion of the material and closes up the crack tip
X - monoclinic
If a crack begins in yttira-stabilised zirconia when the stress at the crack tip reaches a critical level, the crystal structure transforms to the monooclinic structure. This causes a slight X of the material and closes up the crack tip
X - expansion
If a crack begins in yttria-stabilised zirconia when the stress at the crack tip reaches a critical level, the crystal structure transforms to the monoclinic structure. This causes a slight expansion of the material and closes up the crack tip. What properties does this ability give the material?
If a crack begins in yttria-stabilised zirconia when the stress at the crack tip reaches a critical level, the crystal structure transforms to the monoclinic structure. This causes a slight expansion of the material and closes up the crack tip. This give a material which is very:
- hard
- strong (1000MPa flexural strength)
- tough
Is yttria-stabilised zirconia strong enough to be used as a brdieg framework?
yes, yttria-stabilised zirconia is strong enough to be used as a bridge framework
Fabrication of a Zirconia core:
- impression is taken of the preparation and sent to the lab
- a model is cast and then scanned digitially
- the software unit creates a bridge substructure on virtual preparations
- minimum thicknesses of connectors are determined and fabricated
- raw zirconia block is selected for X
- the cut framework is then heat treated at around 850°C to achieve its final physical properties
- this causes a 20% shrinkage but the computer software deals with this during the milling process
- the framework is stained to an appropriate colour
- zirconia core is then veneered with feldspathic porcelain to produce the final restoration
X - milling
Fabrication of a Zirconia core:
- impression is taken of the preparation and sent to the lab
- a model is cast and then scanned digitially
- the software unit creates a bridge substructure on virtual preparations
- minimum thicknesses of connectors are determined and fabricated
- raw zirconia block is selected for milling
- the cut framework is then heat treated at around X°C to achieve its final physical properties
- this causes a 20% shrinkage but the computer software deals with this during the milling process
- the framework is stained to an appropriate colour
- zirconia core is then veneered with feldspathic porcelain to produce the final restoration
X - 850
Fabrication of a Zirconia core:
- impression is taken of the preparation and sent to the lab
- a model is cast and then scanned digitially
- the software unit creates a bridge substructure on virtual preparations
- minimum thicknesses of connectors are determined and fabricated
- raw zirconia block is selected for milling
- the cut framework is then heat treated at around 850°C to achieve its final physical properties
- this causes a X% shrinkage but the computer software deals with this during the milling process
- the framework is stained to an appropriate colour
- zirconia core is then veneered with feldspathic porcelain to produce the final restoration
X - 20
Fabrication of a Zirconia core:
- impression is taken of the preparation and sent to the lab
- a model is cast and then scanned digitially
- the software unit creates a bridge substructure on virtual preparations
- minimum thicknesses of connectors are determined and fabricated
- raw zirconia block is selected for milling
- the cut framework is then heat treated at around 850°C to achieve its final physical properties
- this causes a 20% shrinkage but the computer software deals with this during the milling process
- the framework is X to an appropriate colour
- zirconia core is then veneered with feldspathic porcelain to produce the final restoration
X - stained
Fabrication of a Zirconia core:
- impression is taken of the preparation and sent to the lab
- a model is cast and then scanned digitially
- the software unit creates a bridge substructure on virtual preparations
- minimum thicknesses of connectors are determined and fabricated
- raw zirconia block is selected for milling
- the cut framework is then heat treated at around 850°C to achieve its final physical properties
- this causes a 20% shrinkage but the computer software deals with this during the milling process
- the framework is stained to an appropriate colour
- zirconia core is then veneered with X porcelain to produce the final restoration
X - feldspathic
What can be said about the cost of the equipment needed for fabricating zirconia cored crowns?
expensive equipment is required for zirconia cored crowns
With zirconia cored crowns, there is the potential for the veneering porcelain to X from the core
X - debond
Can you etch or bond zirconia cored crowns?
no, you cannot etch or bond zirconia cored crowns
What can be said about the fit of zirconia cored crowns?
the fit of zirconia cored crowns is generally excellent
Whta are the different materials that can be used for milled core crowns and bridges?
milled core crowns and bridges:
- zirconia
- lithium disilicate
- precious metal
- non-precious metal
- titanium
Ceramics all have a surface X layer for best aesthetics
X - sintered
For the same material, a milled crown will be X than a built up or pressed crown
X - stronger
Fabrication of a milled crown:
- impression and cast taken in the normal way
- cast model up in the normal way
- cast goes into X
- scanned image of the cast available
- opposing cast is scanned and articulated
- crown margin selected
- crown margin adjusted
- crown type selected and placed on “model”
- size and shape of the selected crown is adjusted
- save file
- send to milling machine
X - scanner
Fabrication of a milled crown:
- impression and cast taken in the normal way
- cast model up in the normal way
- cast goes into scanner
- scanned image of the cast available
- X cast is scanned and articulated
- crown margin selected
- crown margin adjusted
- crown type selected and placed on “model”
- size and shape of the selected crown is adjusted
- save file
- send to milling machine
X - opposing
Fabrication of a milled crown:
- impression and cast taken in the normal way
- cast model up in the normal way
- cast goes into scanner
- scanned image of the cast available
- opposing cast is scanned and articulated
- crown margin selected
- crown margin adjusted
- X selected and placed on “model”
- size and shape of the selected crown is adjusted
- save file
- send to milling machine
X - crown type
Cast and pressed ceramics:
- restoration is waxed-up as you would for a metal restoration
- X
- cast from a heated ingot of ceramic (1100°C)
- no sintering occurs, the ceramic ingot is already fully condensed prior to firing
- once devested and cleaned, the restoration is heated to improve its crystal structure - producign crack inhibiting crystals
- this is known as ceraming
- the cast crown can be stained
- more often it is cut back labially and veneered with appropriate feldspathic porcelains
X - invested
Cast and pressed ceramics:
- restoration is waxed-up as you would for a metal restoration
- invested
- cast from a heated ingot of ceramic (X°C)
- no sintering occurs, the ceramic ingot is already fully condensed prior to firing
- once devested and cleaned, the restoration is heated to improve its crystal structure - producing crack inhibiting crystals
- this is known as ceraming
- the cast crown can be stained
- more often it is cut back labially and veneered with appropriate feldspathic porcelains
X - 1100
Cast and pressed ceramics:
- restoration is waxed-up as you would for a metal restoration
- invested
- cast from a heated ingot of ceramic (1100°C)
- no X occurs, the ceramic ingot is already fully condensed prior to firing
- once devested and cleaned, the restoration is heated to improve its crystal structure - producing crack inhibiting crystals
- this is known as ceraming
- the cast crown can be stained
- more often it is cut back labially and veneered with appropriate feldspathic porcelains
X - sintering
Cast and pressed ceramics:
- restoration is waxed-up as you would for a metal restoration
- invested
- cast from a heated ingot of ceramic (1100°C)
- no sintering occurs, the ceramic ingot is already fully condensed prior to firing
- once devested and cleaned, the restoration is heated to improve its X structure - producing crack inhibiting crystals
- this is known as ceraming
- the cast crown can be stained
- more often it is cut back labially and veneered with appropriate feldspathic porcelains
X - crystal
Cast and pressed ceramics:
- restoration is waxed-up as you would for a metal restoration
- invested
- cast from a heated ingot of ceramic (1100°C)
- no sintering occurs, the ceramic ingot is already fully condensed prior to firing
- once devested and cleaned, the restoration is heated to improve its crystal structure - producing crack inhibiting crystals
- this is known as X
- the cast crown can be stained
- more often it is cut back labially and veneered with appropriate feldspathic porcelains
X - ceraming
Cast and pressed ceramics:
- restoration is waxed-up as you would for a metal restoration
- invested
- cast from a heated ingot of ceramic (1100°C)
- no sintering occurs, the ceramic ingot is already fully condensed prior to firing
- once devested and cleaned, the restoration is heated to improve its crystal structure - producing crack inhibiting crystals
- this is known as ceraming
- the cast crown can be stained
- more often it is cut back X and veneered with appropriate feldspathic porcelains
X - labially
What is the ceramic used in cast and pressed ceramic processes?
the ceramic used in cast and pressed ceramics:
- lithium disilicate glass
- leucite reinforced glass
Ceraming is a X stage process
X - 2
What are the 2 stages of ceraming?
ceraming:
- crystal formation where the maximum number of crystal nuclei are formed
- crystal growth to maximise the physical properties
For cast and pressed ceramics, strong materials have X crystal size and high volume fraction of crystals
X - small
For cast and pressed ceramics, strong materials have small crystal size and X volume fraction of crystals
X - high
Lithium disilicate glasses have unique X-like crystals
X - needle
Lithium disilicate glasses have unique needle-like crystals, which makes crack propagation through this material very difficult - giving X flexural strength
X - good/high
Any silica containing ceramic can be etched with X to produce a retentive surface
X - hydrofluoric acid