Dental ceramics Flashcards
What is Kaolin?
- Decorative ceramics contain Kaolin
- It is a clay
- Hydrated Aluminium silicate
- Opaque
- Opacity imp for appearance of final product
Why does Kaolin need to be removed from Dental ceramics?
- Ceramics need to be translucent so Kaolin removed
- Feldspar and silica replace it
What are the components of Decorative ceramic?
- Kaolin 50+%
- Quartz (silica) 15-25%
- Feldspar 15-25%
- Metal oxides <1%
- Glass 0
What are the components of Dental ceramics?
- Kaolin <5%
- Quartz (silica) 12-25%
- Feldspar 70-80%
- Metal oxides 1%
- Glass up to 15%
What are the two types of Feldspar?
- Potash Feldspar (potassium alumina silicate)
- Soda Feldspar (sodium alumina silicate)
What does Feldspar do in dental ceramics?
- Acts as a flux
- Lowers fusion and softening temp of glass
- Has lowest fusing component and flows during firing forming a solid mass around other components
What are dental ceramics considered as ?
- Glasses
What property do metal oxides gives the ceramic?
- Metallic oxide determine colour of ceramic
What colour does Chromium convey to ceramic?
- Green
What colour does Cobalt convey to ceramic?
- Blue
What colour does Copper convey to ceramic?
- Green
What colour does Iron convey to ceramic?
- Brown
What colour does Manganese convey to ceramic?
- Lavender
What colour does Nickel convey to Ceramic?
- Brown
How are conventional dental ceramics used to build up into a restoration?
- Supplied as a powder
- Powder made by heating constituents to high temp >1000oC
- Cool rapidly (Fritting) in water
- This creates cracks and crazing of ceramic mass
- Mill the fritt to fine powder
- Add binder (usually starch)
- Powder is mixed with distilled water and built up into restoration
What do feldspathic ceramics form when heated to 1150oC-1500oC?
- Form leucites around glass phase of ceramic
- Gives powder of known physical and thermal properties
- No further chemical reaction needed during fabrication of restoration
- Powder melts together to form the crown
What is Leucite?
- Potassium aluminium silicate
How are conventional dental ceramics fabricated?
- Ceramic powder mixed with water and applied to die with brush
- Crown built up using different porcelains for dentine and enamel
- They are not tooth coloured
- Crown is heated in furnace to coalesce the powder into ceramic
What is Sintering?
- Heating the crown leads to Sintering
- When the ceramic particles begin to fuse into a single mass
- Occurs just above glass transition temp
What happens during sintering of dental ceramic?
- The glass softens and will coalesce
- Over time controlled diffusion occurs and solid ceramic mass formed
- The material contracts by about 20%
What is meant by the term Coalesce?
- Come together to form one mass or whole
What are some important properties required of conventional dental ceramics?
- Aesthetics
- Chemical Stability
- Biocompatibility
- Thermal Properties
- Dimensional Stability
- Mechanical Properties
Why do ceramics have the best aesthetics properties of any dental restorative material?
- Colour stable
- Very smooth surface
- Retain their surface better than other materials leads to less staining long term
What are the optical properties of dental ceramics?
- Reflectance
- Translucency
- Opacity
- Transparency
- Opalescence
What is the chemical stability of dental ceramics?
- Chemically very stable
- Unaffected by wide pH range found in mouth
- Do not take up stain from food/drink
- Good Biocompatibility so minimal adverse effects on biological tissues
What are the thermal properties of Dental ceramics?
- Sim to tooth substance
- Coefficient of thermal expansion sim to dentine
- Results in low stresses to restorations in mouth during use
- Thermal diffusivity low which protects remaining tooth
What is the dimensional stability of dental ceramics?
- Once fully fired material is very stable
- During fabrication shrinkage occurs which is problem and must be accommodated by technician
- Shrinkage of 20% during firing normal
What are the mechanical properties of conventional dental ceramics?
- High compressive strength
- High hardness (Can lead to abrasion of opposing teeth especially if not glazed)
- Tensile strength – very low
- Flexural strength – very low
- Fracture toughness – very low (All lead to failure during loading)
What is Static fatigue?
- Decrease in strength even in absence of any applied load, it is time dependent