dental ceramics Flashcards
porcelain
all porcelain is ceramic, but not all ceramic is porcelain
kaolin in decorative
Kaolin is a clay
Hydrated Aluminium Silicate
Opaque
Opacity is important for the appearance of the final product
Dental Ceramics need to be translucent so Kaolin is removed and feldspar and silica replace it
so glass is up to 15%
dental ceramics are glasses
Feldspar
Potash feldspar (potassium alumina silicate)
Soda feldspar (sodium alumina silicate)
Acts as a flux
Lowers the fusion and softening temperature of the glass
It is the lowest fusing component and flows during firing forming a solid mass around the other components
Borax
Silica
Metallic Oxides
metal oxides convey colour
Chromium GREEN
Cobalt BLUE
Copper GREEN
Iron BROWN
Manganese LAVENDER
Nickel BROWN
conventional dental ceramics
Conventional dental ceramics are supplied as powder
The powder is made by heating the constituents to a high temperature >1000oC
Cool rapidly (Fritting)
In water creating cracks and crazing of the ceramic mass
Mill the Frit to a fine powder
Add binder
Often starch
The powder is mixed with distilled water and built up into the restoration
Feldspathic ceramics form leucite when heated to 1150-1500oC
Leucite is potassium aluminium silicate
This forms around the glass phase of the ceramic.
Gives a powder of known physical and thermal properties.
No further chemical reaction is required during fabrication of the restoration
The powder melts together to form the crown
ceramic powder is blue or pink
fabrication of the crown
Ceramic powder is mixed with water and applied to the die with a brush
The crown is built up using different porcelains for dentine and enamel
These are not tooth coloured
The crown is heated in a furnace to coalesce the powder into ceramic
pink dentine, blue layered on top
sintering
powder comes together and solidifies, 25% reduction in size
properties of conventional dental ceramics
Aesthetics
Chemical Stability
Biocompatibility
Thermal Properties
Dimensional Stability
Mechanical Properties
aesthetics
Ceramics have the best aesthetic properties of any dental restorative material
Colour Stable
Very smooth surface
Retain their surface better than other materials -> less staining long term
Optical properties
Reflectance
Translucency
Opacity
Transparency
Opalescence
chemical stability
Chemically very stable
Generally unaffected by the wide pH range found in the mouth
Do not take up stain from food/drink
Good BIOCOMPATIBILITY minimal adverse effects on biological tissues
thermal properties
Similar to tooth substance
Coefficient of thermal expansion is similar to dentine
Results in low stresses to the restoration in the mouth during use
Thermal diffusivity is low
Protective of the remaining tooth.
dimensional stability
Once fully fired the material is very stable
During fabrication shrinkage is a problem and must be accommodated for by the technician
Shrinkage of 20% during firing is normal for a conventional feldspathic ceramic crown
mechanical properties
High compressive strength
High hardness
Can lead to abrasion of opposing teeth especially if not glazed
Tensile strength – very low
Flexural strength – very low
Fracture toughness – very low
All lead to failure during loading
Static Fatigue
Time dependant decrease in strength even in the absence of any applied load. Probably due to hydrolysis of Si-O groups within the material, over time in an aqueous environment.
Surface micro-cracks
Can occur during manufacture, finishing or due to occlusal wear. These are areas where fractures can initiate
Slow crack growth
Cyclic fatigue under occlusal forces in a wet environment over time
All of these problems mean that conventional feldspathic ceramics can only be used in low stress areas.
Only anterior crowns.
Not in all patients
Too brittle for use elsewhere
overcoming the problems with conventional ceramics
Aesthetics are good but they need to be stronger
Produce a strong coping, resistant to fracture, and cover in conventional porcelain
Cast or press a block of harder ceramic
Mill a laboratory prepared block of ceramic
strong coping
metal coping
alumina core
zirconia core