Dental Amalgam Flashcards
An alloy, one of the constituents of which is mercury
Silver Paste
An alloy made by mixing Hg with Ag-Sn dental amalgam alloy
Silver Paste
Increases expansion Retards setting time Enhances strength Decrease flow Resist tarnish/corrosion
Silver
Unites with Hg with difficulty Reduces setting time Increases expansion Increases strength and hardness Reduces flow
Copper
Combines readily with Hg Retards setting time Improves platsicity Reduces expansion Increases flow
Tin
Combines readily with Hg Causes expansion increases setting time Increases flow Inhibits oxidation Decreases porosity Provides better clinical performance
Zinc
Other Constituents of Dental Amalgam
Indium (In)
Palladium (Pd)
Mercury (Hg)
Decreases surface tension Reduces amount of mercury necessary Reduces emitted mercury vapor Reduces creep and marginal breadown Increases strength Must be used in admixed alloys 5%
Indium (In)
Reduces corrosion
Greater luster
e.g. Vallant PhD (Ivoclar Vivadent)
0.5%
Palladium (Pd)
Activates reaction
Only pure metal that is liquid at room temperature
Mercury (Hg)
Classification of Amalgam
Amalgam alloy particle geometry and size
Copper content
Zinc content
Irregular particle pack poorly and require a large amount of Hg (50-60%) Precapsulated amalgam (spherical) has 42-45% Hg
Alloy-Mercury ratio
Require less Hg
Smaller surface area, easier to wet
40 to 45%
Spherical Alloys
Reaction of Amalgam
Mercury + Silver-Tin -> Silver-Tin phase + Silver-Mercury phase + Tin-Mercury Phase
Called the gamma phase
Composed of unreacted alloy particle
Silver-Tin Phase
Ag3Sn
Unreacted alloy
Strongest phase and corroded the least
Forms 30% of volume set amalgam
Gamma
The amount of mercury needed to wet all particles and occupy the space between the particles range from ____________ mercury by weight
40-60%
Called the gamma one
Silver-Mercury Phase
Ag2Hg3 Matrix for unreacted alloy Second strongest phase 10 micron grains binding gamma 60% of volume
Gamma 1