Dental Amalgam Flashcards
What is amalgam?
an alloy of any mercury with any other metals
What is dental amalgam?
an alloy of dental mercury (highly purified) with a dental powder alloy formed of silver, tin, copper and sometimes zinc
Dental amalgams are classified according to particle shape into…
- irregular
- spherical
Dental amalgams are classified according to composition into…
- low copper (conventional)
- high copper
High copper composition amalgam is classified into…
- admixed
- unicompositional
What are the properties of silver?
- increased strength
- decreased creep
- increased expansion
- increases reactivity with mercury as well as tarnish and corrosion resistance
- decreases setting time
- 65% min.
What are the properties of tin?
- decreased strength
- increased creep
- decreased expansion
- decreases reactivity with mercury
- increases setting time
- 29% max.
What are the properties of copper?
- increased strength
- decreased creep
- increased expansion
- increases tarnish and corrosion resistance
- 6%max.
What are the properties of zinc?
- it acts as scavenger (deoxidiser) during alloy manufacturing
- however it causes delayed excessive expansion of the filling if contaminated with moisture during trituration or during condensation
How is dental amalgam prepared?
- hand mixing using pestle and mortar
- mechanical mixing using amalgamator with pre-portioning capsules
How to produce an irregular (lathe cut) alloy?
- ingot production: Ag, Cu, Sn & Zn are melted and poured into a mold to form the ingot then the ingot is cooled slowly to allow the formation of the greatest amount of Ag3Sn intermetallic compound (γ-phase). However, the formed ingot is non-homogenous
- homogenisation: to eliminate coring (non homogeneity of the ingot) and hence increasing corrosion resistance, the ingot is heated at 400 degrees for 24 hours to uniformly distribute Ag3Sn (gamma-phase)
- powder production: the ingot is placed in a lathe or by ball milling machine. These methods of cutting induce internal stresses in the alloy particles
- aging or annealing: the freshly cut alloy powder are highly reactive and set rapidly on mixing with mercury due to the stresses induced during cutting. Stresses are removed rapidly by heating the powder at 100 degrees for 1 hour or slowly by storing it at room temperature for several months
How to produce spherical powder?
Ag, Cu, Sn, & Zn are melted and then sprayed into either an inert gas (argon) where the droplets solidify into spheres or water to produce spheroidal particles
What are the advantages of spherical and spheroidal powder?
- better wettability by less mercury/alloy ratio
- superior mechanical properties
- easier condensation
Why should dental mercury be triple distilled?
to be very pure otherwise the surface contaminates and will interfere with the setting reaction (delay it)
What is the amalgamation reaction of low copper alloys?
mixing of the Ag3Sn alloys (γ-phase) with mercury causes the outer layer of the alloy particles to react with the mercury forming two new phases
What is the microstructure of low copper alloys?
it consists of unreacted Ag3Sn (gamma) phase as cores that are surrounded by gamma 1 + gamma 2 phases as a matrix
Why is it beneficial to eliminate gamma 2 phase?
it is the weakest, most corrodible and liable to creep so its elimination leads to an amalgam restoration with superior properties
What is the surface reaction of low copper alloys?
Ag3Sn + Hg –> Ag2Hg3 + Sn8Hg + Ag3Sn
Which phase has the highest corrosion resistance and strongest?
gamma phase
What is the oldest restoration?
Amalgam
How much % is low amalgam?
less than 6%
What is the problem of ingot production?
cored structure that has core
How to eliminate coring?
homogenisation reaction
What is gamma?
Ag3Sn
What is gamma 1?
Ag2Hg3
What is gamma 2?
Sn8Hg