Dent 1.3 Flashcards
what is added to Frit to creat different shades
— Oxides (eg titianium oxide = yellow brown)
what two phases do compositions consist of when coming from the manufacture
Vitreous (glass) phase, and
Crystalline (nuneral/leucite) phase
what are some Characteristics of Crystalin phase
High thermal expansion
Content (10-20%) controls the CTE of the porcelain
contributes strength
when a crown is moved into the oven where it is heated under vacuum and the process called _______ takes place
Sintering (porcelain particles join together by flow on contact as a result of surface energy)
where is a fracture most common when proper bonding is present
fractures in the porcelain
when will a fracture occur trough the oxide layer
If the oxide layer is to thick
CTE of ceramic and metal must be compatible - metal slightly _______ then ceramic to put ceramic in a compression where it is ______
Higher, compatible
CTE
Coefficient of thermal expansion
what are the three stages of free Radical Polymerization
1) Initiation phase
2) propagation stage
3) termination stage
what substances are considered to be Thermoplastic
WAXES
why are waxes considered to have a high degree of THERMAL EXPANSION
due to weak secondary valence forces and transition forces
Define residual stress
internal stresses- independant of applied forces.
what causes residual stress
usually a result of non-uniform heating and cooling
Four properties of Waxes
melting range
tendency to flow
residual stresses
Largest CTE of all dental materials
what is the most accurate way to measure impression materials
By Weight