Denial Ceramic Flashcards
STRUCTURE OF DENTAL PORCELAIN
Why use ceramics?
Appeal of dental ceramics is:
- corrosion resistance (relative insolubility in the mouth)
- surface hardness.
- aesthetics.
Dental porcelains
produced as glass powders featuring particle sizes ranging 1-80 microns.
- the system is non-crystalline and acts as a super-cooled liquid of high viscosity at room temperature.
- structural basis can be understood in terms of vitreous (glass-like) silica SiO2, which has been chemically modified to yield suitable physical and chemical properties.
- modifying agents is normally an oxide, the principal functions of which can be broadly categorised as follows:
Modifying agents
- NETWORK-MODIFYING OXIDES
- NETWORK-FORMING OXIDES
- OPACIFENT OXIDES
- FLUORESCENT OXIDES
Dental porcelain is produced from the fusion of appropriate ratios of these (& other) components,
followed by fritting and grinding to a powder with a suitable range of particle sizes.
In the dental production laboratory
Heat a suitably-shaped agglomerate of porcelain particles to the fusion temperature (ca 950-9800C). Known as ‘firing
•Resulting in fusion of the individual particles without porosity.
•The physical process is one of SINTERING and the driving force is the accompanying reduction of surface energy.
• A volume contraction accompanies the firing process, which may be up to 30%.
Sintering
Sintering is the process of compacting and forming a solid mass of material by heat or pressure without melting it to the point of liquefaction. Sintering happens naturally in mineral deposits or as a manufacturing process used with metals, ceramics, plastics, and other materials.
To fabricate a porcelain crown or an enamel veneer,
Dental porcelain
Brittle material.
•As with all brittle materials tensile strength is reduced from the theoretical value by the presence of flaws such as cracks & pores
•These defects may be on the surface, or within the body of the material.
•Internal porosity may be reduced by firing in a partial vacuum
VACUUM-FIRED PORCELAIN, with improved aesthetics and strength.
Termed as maturity