Degradation Flashcards

1
Q

Define degradation.

A

Loss of structural, mechanical or physical properties over long periods.

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2
Q

How can degradation be caused?

A

Chemical or mechanical processes.

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3
Q

Give an example of chemical degradation.

A

Corrosion of steel to form rust is a process of chemical degradation.

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4
Q

Give an example of mechanical degradation.

A

Propagation of micro-cracks during cyclic loads (i.e. fatigue).

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5
Q

Are mechanical and chemical degradation often coupled?

A

Yes for example steel corrosion crack of metals, where fatigue of fractures in metal is favoured by a corrosive process taking place near the tip of the crack.

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6
Q

Name 3 types of mechanical degradation?

A

1) Fracture
2) Fatigue
3) Creep

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7
Q

What type of deformation is creep?

A

Permanent deformation is similar to plastic deformation.

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8
Q

When does creep happen?

A

In metals at high temperatures (>0.4Tm).

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9
Q

What type of systems experience creep?

A

Turbine rotors in jet engines and steam generators.

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10
Q

When testing for creep what is kept constant?

A

Stress and temperature.

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11
Q

When testing for creep what is measured?

A

The strain is measured and plotted as a function of time.

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12
Q

What are the 3 different areas of a creep curve?

A

1) Primary
2) Secondary
3) Tertiary

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13
Q

What is the primary area on a creep curve?

A

Strain hardening takes place and deformation becomes difficult.

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14
Q

What is the secondary area on a creep curve?

A

Competition between strain hardening and recovery. Longest duration.

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15
Q

What is the tertiary area on a creep curve?

A

Strain rate increases as failure or rupture occurs.

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16
Q

What is corrosion?

A

A reaction between a metal and its environment.

17
Q

What are the losses to the UK economy due to corrosion?

A

5% of GDP.

18
Q

What is dry corrosion?

A

Fast reaction between the surface metal and atmospheric oxygen.

19
Q

Is aluminium reactive?

A

Yes very and forms an impermeable oxide layer which protects it from further oxidation.

20
Q

Is copper reactive?

A

Yes as it reacts with oxygen in the atmosphere to form a protective layer. The green patina is formed of varying mixtures of copper chlorides, sulphides, sulphates and carbonates, depending upon the environment.

21
Q

Which electrode undergoes corrosion?

A

Electrons leave the anode, therefore, corrosion occurs.

22
Q

What happens at the cathode?

A

Electrons arrive and the positive electrolyte ions precipitate.

23
Q

What is standard electrode potential?

A

Two materials are coupled, the one corroding (the anode) is that with the lowest electrode potential.

24
Q

What is rust also known as?

A

Iron hydroxide.

25
Q

How does mill scale form?

A

Hot steel reacts with oxygen in the air to produce an oxide film called mill scale.

26
Q

What does corrosion require?

A

Oxygen and Water

27
Q

Why doesn’t steel reinforcement bars in concrete corrode?

A

The cathodic reaction formed OH but typically cement solution having a high pH meaning they are already rich in OH ions.