Definitions & Decay Flashcards
Stable isotopes
Reference to light elements.
Light elements have a large percentage difference in the masses of their isotopes. Behave differently by various physical & chemical processes.
Examples of stable isotopes
H, C, N, O, S and Cl, Li, B, Si
How to measure isotopes in water
Waters are equilibriums with CO2 and fed into mass spec
Measuring isotopes in carbonates
Carbonate mineral is converted to CO2 gas
Reference standard for oxygen
Waters reference VSMOW
Waters depleted in 18O reference SLAP
Oxygen in carbonates reference VSMOW or VPDB
VSMOW
Vienna standard mean ocean water
SLAP
Standard light Antarctic precipitation
VPDB
Vienna pee dee belemnite
Reference standard for hydrogen
Rations are referred to VSMOW
Reference standard for Carbon
Referenced to VPDB
Reference of S
To CDT (canon diablo troilite)
Reference N, NO2 and He
Atmospheric nitrogen
Reference chlorine
SMOC (standard mean ocean chloride)
3 ways for thermodynamic fractionation
1) equilibrium physiochemical exchange
2) non- equilibrium reactions (kinetic controlled)
3) molecular diffusion
Molecules with a ______ isotope can diffuse out of a system more rapid than a molecule with a _____ isotope
Light
Heavy