Definitions and Formulae (amount of substance 1) Flashcards

1
Q

definition of an atom

A

the smallest part of an element that can exist

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2
Q

definition of an element

A

a substance made of only one type of atom

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3
Q

definition of an ion

A

an an atom which has lost or gained electrons

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4
Q

definition of a molecule

A

a substance which contains atoms joined by covalent bonds

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5
Q

definition of a compound

A

a substance containing more than one type of atom chemically combined

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6
Q

define Relative Atomic Mass (Ar)

A

the average mass of one atom compared with 1/12 of the mass of an atom of carbon-12

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7
Q

define Relative Molecular Mass (Mr)

A

the average mass of one molecule compared with 1/12 of the mass of an atom of carbon-12

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8
Q

what is the formula to calculate % composition

A

% composition = rfm of element/rfm of compound x 100

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9
Q

what is an anhydrous salt

A

without water/dry solid

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10
Q

what is a hydrated salt

A

lattice of ions with water molecules trapped within (water of crystallisation - number of water molecules)

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11
Q

how can you determine the moles of water in a hydrated salt

A
  • measure the mass of the hydrated salt
  • measure the mass of empty crucible
  • measure mass of crucible and hydrated salt
  • do the mass of (hydrated salt and crucible) - mass of crucible
  • heat the crucible until it reaches a constant mass
  • mass of (anhydrous salt + crucible) - mass of empty crucible
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12
Q

how do you calculate the mass of an individual particle

A
  • 1 mole of any substance weighs the same as the Mr of that substance in grams

mass of one ion = Mr/avagadros constant

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13
Q

what is the limiting reactant

A

it is the reactant which is completely used up by the end of the reaction and it determines how much product is formed

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14
Q

how do you calculate percentage yield

A

% yield = actual mass of product / theoretical mass of product x 100

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15
Q

why is the percentage yield never 100%

A
  • reaction is incomplete
  • loss of products e.g. when transferring
  • reaction is reversible
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16
Q

why is the percentage yield very rarely more than 100%

A
  • failure to dry a solid to remove solvent
17
Q

how do you calculate atom economy

A

% atom economy = Mr of useful product / sum of Mr’s of all reactants x 100

18
Q

what is atom economy

A
  • measurement of chemical efficiency
  • cannot be altered
  • indicated wasted atoms
  • e.g. fermentation of glucose
19
Q

when is the atom economy 100%

A

any time there is a SINGLE PRODUCT, the atom economy has to be 100%