Definitions Flashcards
Enthalpy change of formation
Energy transferred when one mole of a compound is formed from its elements under standard conditions, all reactants and products being in their standard states
Enthalpy of atomisation
Enthalpy change when one mole of gaseous atoms is formed from the element in its standard state
First ionisation enthalpy
Enthalpy change required to remove one mole of electrons from one mole of gaseous atoms to form one mole of gaseous ions with a 1+ charge
Second ionisation enthalpy
And Sophie change required to remove one mole of electrons from one mole of gaseous 1+ ions to produce one mole of gaseous 2+ ions
First electron affinity
Enthalpy change that occurs when one mole of gaseous atoms gain is one mole of electrons to form one mole of gaseous ions with a 1- charge
First electron affinity is exothermic for atoms that normally gain electrons to form negative ions, because the ion is more stable than the atom and there is an attraction between the nucleus and the electron
Second electron affinity
Enthalpy change when one mole of gaseous 1- ions gain one electron per ion to produce gases 2- ions
Second electron affinity for oxygen is endothermic because it takes in energy to overcome the proportional force between the negative ion and the electron
Enthalpy change of hydration
Enthalpy change when one mole of gaseous ions dissolved in water
Enthalpy change of solution
Enthalpy change when one mole of solute dissolves in water