Definitions Flashcards

1
Q

Isotopes

A

Atoms of the same element that have a different number of neutrons

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2
Q

Relative isotopic mass

A

Mass of an atom of an isotope compared to 1/12 the mass of an atom of carbon-12

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3
Q

Relative atomic mass

A

Weighted mean mass of an atom compared to 1/12 the mass of an atom of carbon-12

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4
Q

Mole

A

Amount of any substance that has the same number of particles as exactly 12g of carbon-12

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5
Q

Molar mass

A

Mass of 1 mol of substance

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6
Q

Salt

A

Chemical compound formed when the H ion of an acid is replaced with a metal or ammonium ion

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7
Q

Hydrated

A

Contains waters of crystallisation

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8
Q

Water of crystallisation

A

Water molecules in an ionic lattice

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9
Q

Acid

A

Proton donor

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10
Q

Base

A

Proton acceptor

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11
Q

Alkali

A

Soluable base

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12
Q

Disproportionation

A

A reaction where the same element both oxidises and reduces

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13
Q

1st Ionisation energy

A

Energy required to remove one mole of electrons from one mole of gaseous atoms to form one mole of +1 gaseous ions

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14
Q

Orbital

A

A region of space which can take a max of 2 electrons with paired opposing spins

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15
Q

Isoelectric

A

Same electron arrangement but different elements

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16
Q

Covalent bonding

A

The electrostatic attract between the positive nuclei of one atom and a pair of shared electrons

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17
Q

Dative covalent bond

A

When one atom supplies both electrons for the bond

18
Q

Ionic bonding

A

The electrostatic attraction between oppositely charged ions

19
Q

Electronegativity

A

The ability of an element to attract a pair of electrons from a bond

20
Q

Periodicity

A

A property that has a pattern across a period that is repeated across successive periods

21
Q

Giant structure

A

Has no fixed size so can continuously add atoms to the same structure

22
Q

Average bond enthalpy

A

Energy required to break one mole of bonds in a gaseous molecule

23
Q

Standard enthalpy change of formation

A

The enthalpy change when one mole of a compound is made from its elements in their standard state under standard conditions (1 atm and 25 degrees)

24
Q

Standard enthalpy change of combustions

A

Enthalpy change when one mole of substance undergoes complete combustion under standard conditions

25
Q

Standard enthalpy change for neutralisation

A

Enthalpy change on the formation of one mole of water from the neutralisation of acid with an alkali under standard conditions

26
Q

Hesse’s law

A

States that an enthalpy change for a reaction is independant of the route taken (providing the initial and final condition are the same)

27
Q

Heterogenous catalyst

A

A catalyst that is in a different phase (physical state) to the reactants

28
Q

Homogenous catalyst

A

Same phase as reactants

29
Q

Dynamic equilibrium

A

A reversible reaction where the rate of the forward reaction is equal to the rate of the backward reaction

30
Q

Structural isomers

A

Same molecular formule but different structural formula

31
Q

Aliphatic

A

Straight chains only

32
Q

Homologous series

A

Compounds with the same functional group and general formula but successive members differ by CH2

33
Q

Functional group

A

An atom or group of atoms in a compound that determine the characteristic reactions of the molece

34
Q

Radical

A

An atom of group of atoms with an unpaired electron

35
Q

Homolytic fission

A

Each bonding atom receives one electron from the bonding pair forming two radicals

36
Q

Isomer

A

Compounds with the same molecular formula but different chemical structures

37
Q

Stereoisomers

A

Same structural formula but a different arrangement in space

38
Q

Electrophile

A

An electron pair acceptor

39
Q

Makownikoff’s rule

A

The carbocation with the most alkyl groups on the C with the + sign will form as it will be the most stable

40
Q

Nucleophile:

A

An electron pair donor

41
Q

Volatility

A

Indicates how easily a liquid will change into a gas

42
Q

Le Chatelier’s principle

A

The position of equilibrium will shift so as to minimise the effect of any change in condition