Definitions Flashcards

1
Q

Isolated Diene

A

The double bonds are separated by more than one single bond C=C-C-C=C

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2
Q

Conjugated Diene

A

The double bonds are separated by one single bond C=C-C=C

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3
Q

Cumulated Diene

A

The double bonds are not separated by any single bonds -C=C=C- (Allene)

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4
Q

Lewis Acid

A

Electron acceptor (electrophile)

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5
Q

Lewis Base

A

Electron donor (nucleophile)

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6
Q

Inductive Effect

A

When a carbocation is more stable because other carbons are sharing electrons thru sigma bonds (covalent)

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7
Q

Torsional Strain

A

When conformations of torsion angles between adjacent bonds are other than 60 degrees. A type of steric strain.

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8
Q

Steric Strain

A

van der Waals forces: when bulky groups repel each other/ get in the way

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9
Q

Angle Strain

A

When a bond angle is tighter than is should be (less than 109.5 in alkanes)

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10
Q

Hyperconjugation

A

pi bond interaction with adjacent bonds

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